Frederik Doktor S Simonsen, Pernille A Jensen, Anders W Skov, Rijutha Jaganathan, John D Thrower, Liv Hornekær
{"title":"H<sub>2</sub> catalysis through superhydrogenation of interstellar polycyclic aromatic hydrocarbons.","authors":"Frederik Doktor S Simonsen, Pernille A Jensen, Anders W Skov, Rijutha Jaganathan, John D Thrower, Liv Hornekær","doi":"10.1017/S1743921320000034","DOIUrl":null,"url":null,"abstract":"<p><p>Experimental data showing superhydrogation of neutral polycyclic aromatic hydrocarbons (PAHs) coronene, pentacene and pentacenequinone is presented. PAH monolayers were prepared on a highly oriented pyrolytic graphite surface and subsequently exposed to a beam of atomic hydrogen. The superhydrogenated PAH species were examined via temperature programmed desorption measurements. Stable intermediate superhydrogenation degrees as well as fully superhydrogenated species are observed and the initial reaction cross section for coronene has been determined.</p>","PeriodicalId":74548,"journal":{"name":"Proceedings of the International Astronomical Union. International Astronomical Union","volume":"15 Suppl 350","pages":"264-266"},"PeriodicalIF":0.0000,"publicationDate":"2019-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7116204/pdf/EMS92585.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of the International Astronomical Union. International Astronomical Union","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1017/S1743921320000034","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2020/10/12 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Experimental data showing superhydrogation of neutral polycyclic aromatic hydrocarbons (PAHs) coronene, pentacene and pentacenequinone is presented. PAH monolayers were prepared on a highly oriented pyrolytic graphite surface and subsequently exposed to a beam of atomic hydrogen. The superhydrogenated PAH species were examined via temperature programmed desorption measurements. Stable intermediate superhydrogenation degrees as well as fully superhydrogenated species are observed and the initial reaction cross section for coronene has been determined.
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