Initial Dynamic Susceptibility of Maghemite Nanoparticles Dispersed in Surface-Treated Polymeric Template.

A F R Rodriguez, R F Lacerda, L E Maggi, Hory Mohammadpour, Mohammad Niyaifar, Shahrokh Niyaifar, Judes G Santos, M A Morales
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Abstract

Magnetic nanocomposites based on maghemite nanoparticles supported (ex situ route) on styrene- divinilbenzene (Sty-DVB) copolymer templates were produced and characterized for their structure and morphology. The as-produced nanocomposites were further chemically-treated with different oxidant agents and surface-coated with stearic acid. X-ray diffraction and transmission electron microscopy data show that the incorporated nanoparticles are preserved despite the aggressive chemical treatments employed. From the dynamical susceptibility measurements performed on the nanocomposites, the values of the saturation magnetization (76 emu/g) and the effective magnetic anisotropy (1.7 × 10⁴ J/m³) were obtained, in excellent agreement with the values reported in the literature for maghemite. This finding strongly supports the preservation of the magnetic properties of the supported nanosized maghemite throughout the entire samples' processing.
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磁赤铁矿纳米颗粒分散在表面处理聚合物模板中的初始动态磁化率。
制备了基于磁赤铁矿的磁性纳米复合材料,并对其结构和形貌进行了表征。制备的纳米复合材料进一步用不同的氧化剂进行化学处理,并表面涂覆硬脂酸。x射线衍射和透射电子显微镜数据表明,尽管采用了积极的化学处理,但掺入的纳米颗粒仍被保存下来。通过对纳米复合材料进行的动态磁化率测量,获得了饱和磁化强度(76 emu/g)和有效磁各向异性(1.7 × 10⁴J/m³)的值,与文献中报道的磁铁矿的值非常一致。这一发现有力地支持了在整个样品处理过程中,负载的纳米级磁铁矿的磁性能的保存。
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来源期刊
Journal of nanoscience and nanotechnology
Journal of nanoscience and nanotechnology 工程技术-材料科学:综合
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审稿时长
3.6 months
期刊介绍: JNN is a multidisciplinary peer-reviewed journal covering fundamental and applied research in all disciplines of science, engineering and medicine. JNN publishes all aspects of nanoscale science and technology dealing with materials synthesis, processing, nanofabrication, nanoprobes, spectroscopy, properties, biological systems, nanostructures, theory and computation, nanoelectronics, nano-optics, nano-mechanics, nanodevices, nanobiotechnology, nanomedicine, nanotoxicology.
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