Effect of Ce3+ Ions Doped NiFe₂O₄ Magnetic Nanoparticles on Photocatalytic Degradation of Rhodamine B and Antibacterial Activities.

Abstract

In this study, spinel NiCe_xFe_2-XO₄ (x = 0.0 - 0.5) nanoparticles (NPs) was synthesized by microwave combustion technique (MCT) utilizing the fuel of Aloe vera plant extract. The establishment of spinel cubic crystal structure was ensured by powder X-ray diffraction (PXRD) technique. The particles like nanostructured morphology were confirmed by high-resolution scanning electron microscope (HRSEM). Energy dispersive X-ray (EDX) studies confirmed the formation of spinel ferrite structure and ensured that no other elements were present. Magnetic parameters such as remanant magnetisation (Mr), coercivity (He) and saturation magnetization (Ms) were calculated from the magnetic hysteresis (M-H) loops, which exhibited ferromagnetic behaviour. The photocatalytic behavior was investigated by visible light treatment for the photocatalytic degradation (PCD) of rhodamine B (Rh-B) dye and the sample NiCe_0.3Fe_1.7O₄ exhibits higher PCD efficiency (93.88%) than other compositions. The antibacterial activities of gram-positive S. aureus, B. subtilis, gramnegative K. pneumonia and E. coli have been investigated using undoped and Ce³⁺ substituted NiFe₂O₄ NPs and observed higher activity, which indicated that, they can be used in the bio-medical applications.