A Simple Dilution Method for Preparation of Different Aggregates from Oleic Acid/CHAPSO Bicelles.

Shogo Taguchi, Yasuaki Tachibana, Yuta Kimura, Takuji Yamamoto, Hiroshi Umakoshi
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引用次数: 1

Abstract

We evaluated the effect of dilution on both the size and packing density of aggregates prepared from a fatty acid (oleic acid, OA)/detergent (3-[(3-cholamidopropyl)dimethylammonio]-2-hydroxypropane sulfonate (CHAPSO)) bicelle as a parent for functional membrane materials. The sizes of the aggregates formed at different molar ratios, XOA(= [OA]/([OA]+[CHAPSO])), of 0.3 and 0.7 and their parent bicelles were measured by dynamic light scattering and transmission electron microscopy; their packing density was evaluated by deconvolution of the fluorescence spectrum, where Laurdan molecules were used as a probe. The experimental results showed that the bicelles formed aggregates upon dilution because of the hydration of CHAPSO. The packing density of the nano-ordered aggregate formed at XOA = 0.3 was much greater than that of the aggregate formed at XOA = 0.7, implying the formation of an ordered aggregate under the condition of XOA = 0.3.

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油酸/CHAPSO小柱制备不同聚集体的简单稀释法。
我们评估了稀释对以脂肪酸(油酸,OA)/洗涤剂(3-[(3-胆酰胺丙基)二甲酰胺]-2-羟丙烷磺酸(CHAPSO))为母体制备的聚体尺寸和堆积密度的影响。采用动态光散射和透射电镜测量了不同摩尔比XOA(= [OA]/([OA]+[CHAPSO]))为0.3和0.7时形成的聚集体及其母细胞的大小;通过荧光光谱的反褶积来评估它们的堆积密度,其中Laurdan分子被用作探针。实验结果表明,由于CHAPSO的水化作用,小束在稀释后形成聚集体。在XOA = 0.3时形成的纳米有序骨料的堆积密度远大于在XOA = 0.7时形成的纳米有序骨料,说明在XOA = 0.3条件下形成了有序骨料。
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来源期刊
Journal of nanoscience and nanotechnology
Journal of nanoscience and nanotechnology 工程技术-材料科学:综合
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审稿时长
3.6 months
期刊介绍: JNN is a multidisciplinary peer-reviewed journal covering fundamental and applied research in all disciplines of science, engineering and medicine. JNN publishes all aspects of nanoscale science and technology dealing with materials synthesis, processing, nanofabrication, nanoprobes, spectroscopy, properties, biological systems, nanostructures, theory and computation, nanoelectronics, nano-optics, nano-mechanics, nanodevices, nanobiotechnology, nanomedicine, nanotoxicology.
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