Additive free, N-heterocyclic nitrenium catalyzed photoreduction of cycloketone oxime esters†

Xiao-Di Su , Zhu-Sheng Yang , Wei Gong , Zhi-Xiang Wang , Xiang-Yu Chen
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Abstract

We report that N-heterocyclic nitreniums (NHNs) can be used as ideal charge transfer complex catalysts in the absence of any additives for the photoactivation of cycloketone oxime esters, where the...

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无添加剂,n -杂环氮催化光还原环酮肟酯†
我们报道了在不存在任何添加剂的情况下,N-杂环氮(NHN)可以用作理想的电荷转移络合物催化剂,用于环酮肟酯的光活化,其中NHN阳离子充当催化电子受体,反离子I−是催化电子供体。这种策略能够合成各种三取代烯烃和杂环。
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