A. V. Grekova, P. O. Ivanchenko, T. V. Koksharova, Ya. F. Burdina
{"title":"Initiation of Polymerization of Vinyl Monomers by Copper(II) Glycylglycinate and Aminoacetate Complexes with 4-Phenylthiosemicarbazide","authors":"A. V. Grekova, P. O. Ivanchenko, T. V. Koksharova, Ya. F. Burdina","doi":"10.1007/s11237-022-09724-7","DOIUrl":null,"url":null,"abstract":"<div><div><p>The ability of copper(II) complexes with 4-phenylthiosemicarbazide and amino acid anions to act as initiators of polymerization of methyl methacrylate and styrene is shown. It was found that the activation energies of polymerization and initiation in the presence of copper(II) complexes are significantly reduced in comparison with the process of thermal initiation. It is established that polymerization of methyl methacrylate initiated by the studied complexes resulted in the formation of syndiotactic polymer.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":"58 1","pages":"70 - 74"},"PeriodicalIF":0.7000,"publicationDate":"2022-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-022-09724-7","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The ability of copper(II) complexes with 4-phenylthiosemicarbazide and amino acid anions to act as initiators of polymerization of methyl methacrylate and styrene is shown. It was found that the activation energies of polymerization and initiation in the presence of copper(II) complexes are significantly reduced in comparison with the process of thermal initiation. It is established that polymerization of methyl methacrylate initiated by the studied complexes resulted in the formation of syndiotactic polymer.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
