{"title":"Complexation on the Oxide Surfaces: Adsorption of Biomolecules from Aqueous Solutions: A Review","authors":"N. M. Vlasova, O. V. Markitan","doi":"10.1007/s11237-022-09716-7","DOIUrl":null,"url":null,"abstract":"<div><div><p>Available approaches for quantitative description of the complexation processes on the surfaces of oxides in solutions are analyzed. The equilibrium constants for adsorption interactions of a number of amino acids with titanium and cerium dioxides in aqueous solutions are determined using these approaches. The mechanism of sorption of amino acids on TiO<sub>2</sub> and CeO<sub>2</sub> is proposed and features of protein sorption on the oxide sorbents are specified.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":"58 1","pages":"1 - 14"},"PeriodicalIF":0.7000,"publicationDate":"2022-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-022-09716-7","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 2
Abstract
Available approaches for quantitative description of the complexation processes on the surfaces of oxides in solutions are analyzed. The equilibrium constants for adsorption interactions of a number of amino acids with titanium and cerium dioxides in aqueous solutions are determined using these approaches. The mechanism of sorption of amino acids on TiO2 and CeO2 is proposed and features of protein sorption on the oxide sorbents are specified.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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