Advanced microplastic monitoring using Raman spectroscopy with a combination of nanostructure-based substrates.

IF 8.6 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Journal of Nanostructure in Chemistry Pub Date : 2022-01-01 Epub Date: 2022-06-18 DOI:10.1007/s40097-022-00506-0
Nguyễn Hoàng Ly, Moon-Kyung Kim, Hyewon Lee, Cheolmin Lee, Sang Jun Son, Kyung-Duk Zoh, Yasser Vasseghian, Sang-Woo Joo
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Abstract

Micro(nano)plastic (MNP) pollutants have not only impacted human health directly, but are also associated with numerous chemical contaminants that increase toxicity in the natural environment. Most recent research about increasing plastic pollutants in natural environments have focused on the toxic effects of MNPs in water, the atmosphere, and soil. The methodologies of MNP identification have been extensively developed for actual applications, but they still require further study, including on-site detection. This review article provides a comprehensive update on the facile detection of MNPs by Raman spectroscopy, which aims at early diagnosis of potential risks and human health impacts. In particular, Raman imaging and nanostructure-enhanced Raman scattering have emerged as effective analytical technologies for identifying MNPs in an environment. Here, the authors give an update on the latest advances in plasmonic nanostructured materials-assisted SERS substrates utilized for the detection of MNP particles present in environmental samples. Moreover, this work describes different plasmonic materials-including pure noble metal nanostructured materials and hybrid nanomaterials-that have been used to fabricate and develop SERS platforms to obtain the identifying MNP particles at low concentrations. Plasmonic nanostructure-enhanced materials consisting of pure noble metals and hybrid nanomaterials can significantly enhance the surface-enhanced Raman scattering (SERS) spectra signals of pollutant analytes due to their localized hot spots. This concise topical review also provides updates on recent developments and trends in MNP detection by means of SERS using a variety of unique materials, along with three-dimensional (3D) SERS substrates, nanopipettes, and microfluidic chips. A novel material-assisted spectral Raman technique and its effective application are also introduced for selective monitoring and trace detection of MNPs in indoor and outdoor environments.

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利用拉曼光谱结合纳米结构基底进行先进的微塑料监测。
微(纳米)塑料(MNP)污染物不仅直接影响人类健康,还与许多化学污染物相关联,增加了自然环境中的毒性。最近关于自然环境中塑料污染物增加的研究主要集中在水、大气和土壤中的 MNP 毒性效应。MNP 识别方法已在实际应用中得到广泛发展,但仍需进一步研究,包括现场检测。这篇综述文章全面介绍了利用拉曼光谱轻松检测 MNPs 的最新进展,旨在对潜在风险和人类健康影响进行早期诊断。特别是,拉曼成像和纳米结构增强拉曼散射已成为识别环境中 MNPs 的有效分析技术。在此,作者介绍了用于检测环境样本中存在的 MNP 粒子的等离子纳米结构材料辅助 SERS 基底的最新进展。此外,这项工作还介绍了不同的质子材料,包括纯贵金属纳米结构材料和混合纳米材料,这些材料已被用于制造和开发 SERS 平台,以获得低浓度的可识别 MNP 粒子。由纯贵金属和混合纳米材料组成的等离子纳米结构增强材料由于其局部热点,可以显著增强污染物分析物的表面增强拉曼散射(SERS)光谱信号。这篇简明的专题综述还介绍了利用各种独特材料以及三维(3D)SERS 基质、纳米吸头和微流控芯片通过 SERS 检测 MNP 的最新进展和趋势。此外,还介绍了一种新型材料辅助光谱拉曼技术及其在室内外环境中选择性监测和痕量检测 MNPs 的有效应用:
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来源期刊
CiteScore
18.20
自引率
3.00%
发文量
61
审稿时长
22 days
期刊介绍: The Journal of Nanostructure in Chemistry (JNC) publishes cutting-edge research at the intersections of chemistry, biology, biotechnology, materials science, physics, and engineering. It features high-quality research, perspectives, and review articles covering various disciplines within the natural sciences, biomedicine, and engineering. The journal's scope includes, but is not limited to, the following topics: Target drug and gene delivery Tissue engineering and regenerative medicine Cancer therapy Diagnosis and Bioimaging Electrochemical detection and sensing Food industry and packaging Environments (catalyst, coatings, and water treatment) Energy (fuel cells, capacitor, laser)
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Correction: Efficient dye degradation, antimicrobial behavior and molecular docking analysis of gold (Au) and cellulose nanocrystals (CNC)-doped strontium oxide nanocomposites Photocatalytic decomposition of methylene blue and rhodamine B using Ag–Ag2SeO3/Ppy nano‑photocatalyst from aqueous solutions: experimental design optimization Ag-doped ZnO nanoparticles synthesized through green method using Artemisia turcomanica extract induce cytotoxicity and apoptotic activities against AGS cancer cells: an in vitro study Correction: Exploiting the high conjugation capacity of creatinine on 3,3′-dithiodipropionic acid di(N-hydroxysuccinimide ester) functionalized gold nanoparticles towards sensitive determination of mercury (II) ion in water Fabrication of reduced graphene oxide-doped carbon aerogels from water hyacinth for removal of methylene blue in water and energy storage
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