A Review on Polyethersulfone Membranes in Polar Organic Chemical Integrative Samplers: Preparation, Characterization and Innovation.

IF 5.5 3区材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-01-01 Epub Date: 2022-10-20 DOI:10.1080/10408347.2022.2131374

Henry MacKeown, Barbara Benedetti, Chiara Scapuzzi, Marina Di Carro, Emanuele Magi

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Abstract

The membranes in polar organic chemical integrative samplers (POCIS) enclose the receiving sorbent and protect it from coming into direct contact with the environmental matrix. They have a crucial role in extending the kinetic regime of contaminant uptake, by slowing down their diffusion between the water phase and the receiving phase. The drive to improve passive sampling requires membranes with better design and enhanced performances. In this review, the preparation of standard polyethersulfone (PES) membranes for POCIS is presented, as well as methods to evaluate their composition, morphology, structure, and performance. Generally, only supplier-related morphological and structural data are provided, such as membrane type, thickness, surface area, and pore diameter. The issues related to the use of PES membranes in POCIS applications are exposed. Finally, alternative membranes to PES in POCIS are also discussed, although no better membrane has yet been developed. This review highlights the urge for more membrane characterization details and a better comprehension of the mechanisms which underlay their behavior and performance, to improve membrane selection and optimize passive sampler development.

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极性有机化学综合采样器中的聚醚砜膜综述：制备、表征和创新。

极性有机化学综合采样器（POCIS）中的膜将接收吸附剂封闭起来，防止其与环境基质直接接触。它们通过减缓污染物在水相和接收相之间的扩散，在延长污染物吸收动力学机制方面发挥着至关重要的作用。改进被动采样需要设计更好、性能更强的膜。本综述介绍了用于 POCIS 的标准聚醚砜（PES）膜的制备方法，以及评估其成分、形态、结构和性能的方法。一般来说，只提供与供应商相关的形态和结构数据，如膜类型、厚度、表面积和孔径。与在 POCIS 应用中使用聚醚砜膜有关的问题也暴露无遗。最后，还讨论了 POCIS 中 PES 的替代膜，尽管目前还没有开发出更好的膜。这篇综述强调了需要更多的膜特性细节和更好地理解其行为和性能的机制，以改进膜的选择和优化被动采样器的开发。

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来源期刊

ACS Applied Energy Materials Materials Science-Materials Chemistry

CiteScore

10.30

自引率

6.20%

发文量

1368

期刊介绍： ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.

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