A novel approach to interpret quasi-collimated beam results to support design and scale-up of vacuum UV based AOPs

Abstract

UV-C at 254 nm and vacuum UV (VUV) at 185 nm are the two major emission lines of a low-pressure mercury lamp. Upon absorption of VUV photons, water molecules and selected inorganic anions generate hydroxyl (HO^.) and other redox radicals, both capable of degrading organic micropollutants (OMPs), thereby offering the opportunity to reduce H₂O₂ and energy consumption in UV-based advanced oxidation process (AOP). To be successfully scaled-up, the dual-wavelength VUV+UV/H₂O₂ AOP requires laboratory-scale experiments to establish design criteria. The figures of merit typically used for reporting and interpreting quasi-collimated beam results for UV-based AOPs (time, dose, absorbed energy and E_EO) are insufficient and inaccurate when employed for dual-wavelength AOP such as the VUV+UV/H₂O₂ AOP, and do not support system scale-up. In this study, we introduce a novel figure of merit, useful absorbed energy (uAE), defined as fraction of absorbed energy that results in the generation of oxidative radicals. Here, results of quasi-collimated beam VUV+UV/H₂O₂ AOP experiments on four different water matrices are used to introduce 2D plots that employ both uAE_UV and uAE_VUV as a novel method to represent laboratory-scale experiments of VUV+UV/H₂O₂ AOP and demonstrate how the 2D plots sufficiently support scale-up of the AOP.