Regulation of the Degree of Interpenetration in Metal–Organic Frameworks

IF 7.1 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Topics in Current Chemistry Pub Date : 2019-12-02 DOI:10.1007/s41061-019-0268-x
Gaurav Verma, Sydney Butikofer, Sanjay Kumar, Shengqian Ma
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引用次数: 22

Abstract

Interpenetration in metal–organic frameworks (MOFs) can have significant impacts on the structure, porous nature, and functional applications of MOFs. Considered to be disadvantageous in the initial phases leading to a decrease in surface area, interpenetration has proved to be highly useful for modulation of pore size and selective separation of gases. The importance of interpenetration has been realized over the last decade, and numerous approaches to graft interpenetration and utilize it for improved functions and applications have been achieved. Several factors such as temperature, solvent system, time duration and steric aspects of the ligands have been utilized to regulate the degree of interpenetration (DOI). In this review, we summarize recent advances in regulating the DOI in MOFs and its impact on the resulting properties.

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金属-有机骨架中相互渗透程度的调控
金属-有机骨架(MOFs)的相互渗透对其结构、多孔性和功能应用具有重要影响。在初始阶段,互渗被认为是不利的,导致表面积的减少,但事实证明,互渗对孔径的调节和气体的选择性分离非常有用。在过去的十年中,人们已经认识到相互渗透的重要性,并且已经实现了许多嫁接相互渗透并利用它来改进功能和应用的方法。温度、溶剂体系、时间持续时间和配体的空间等因素都被用来调节相互渗透程度(DOI)。在本文中,我们总结了调控MOFs中DOI的最新进展及其对MOFs性能的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Topics in Current Chemistry
Topics in Current Chemistry Chemistry-General Chemistry
CiteScore
13.70
自引率
1.20%
发文量
48
期刊介绍: Topics in Current Chemistry is a journal that presents critical reviews of present and future trends in modern chemical research. It covers all areas of chemical science, including interactions with related disciplines like biology, medicine, physics, and materials science. The articles in this journal are organized into thematic collections, offering a comprehensive perspective on emerging research to non-specialist readers in academia or industry. Each review article focuses on one aspect of the topic and provides a critical survey, placing it in the context of the collection. Selected examples highlight significant developments from the past 5 to 10 years. Instead of providing an exhaustive summary or extensive data, the articles concentrate on methodological thinking. This approach allows non-specialist readers to understand the information fully and presents the potential prospects for future developments.
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