Synthesis and electroanalytical applications of a novel hydrazinecarbothioamide derivative molecule

IF 2.1 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Chemical Papers Pub Date : 2023-07-17 DOI:10.1007/s11696-023-02968-0
Oguz Özbek, Serkan Ören, Meliha Burcu Gürdere, Ömer Isildak, Mustafa Ceylan
{"title":"Synthesis and electroanalytical applications of a novel hydrazinecarbothioamide derivative molecule","authors":"Oguz Özbek,&nbsp;Serkan Ören,&nbsp;Meliha Burcu Gürdere,&nbsp;Ömer Isildak,&nbsp;Mustafa Ceylan","doi":"10.1007/s11696-023-02968-0","DOIUrl":null,"url":null,"abstract":"<div><p>Molecules containing multiple donor atoms such as nitrogen, oxygen and sulfur in their structure are more preferred as ionophores in the preparation of ion-selective electrodes. In this study, a new hydrazinecarbotioamide derivative molecule was synthesized as an ionophore and characterized using NMR, FT–IR and elemental analysis techniques. The potentiometric electrodes prepared with the synthesized new molecule (ionophore) exhibited selectivity towards lead(II) ions. This novel electrode had a low detection limit of 6.98 × 10<sup>–7</sup> M over a wide concentration range of 1.0 × 10<sup>–6</sup>–1.0 × 10<sup>–1</sup> M. Obtained experimental data showed that the electrode has good repeatability, good selectivity and good stability. At the same time, it could work in a wide pH range without being affected by pH changes. The analytical applications of the developed electrode, whose potentiometric performance parameters were studied, were carried out in different water samples.</p></div>","PeriodicalId":55265,"journal":{"name":"Chemical Papers","volume":"77 11","pages":"6679 - 6687"},"PeriodicalIF":2.1000,"publicationDate":"2023-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11696-023-02968-0.pdf","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Papers","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11696-023-02968-0","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 1

Abstract

Molecules containing multiple donor atoms such as nitrogen, oxygen and sulfur in their structure are more preferred as ionophores in the preparation of ion-selective electrodes. In this study, a new hydrazinecarbotioamide derivative molecule was synthesized as an ionophore and characterized using NMR, FT–IR and elemental analysis techniques. The potentiometric electrodes prepared with the synthesized new molecule (ionophore) exhibited selectivity towards lead(II) ions. This novel electrode had a low detection limit of 6.98 × 10–7 M over a wide concentration range of 1.0 × 10–6–1.0 × 10–1 M. Obtained experimental data showed that the electrode has good repeatability, good selectivity and good stability. At the same time, it could work in a wide pH range without being affected by pH changes. The analytical applications of the developed electrode, whose potentiometric performance parameters were studied, were carried out in different water samples.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
一种新型肼甲硫酰胺衍生物分子的合成及电分析应用
在离子选择电极的制备中,在其结构中含有多个供体原子如氮、氧和硫的分子更优选作为离子载体。在本研究中,合成了一种新的肼基碳硫酰胺衍生物分子作为离子载体,并用NMR、FT–IR和元素分析技术对其进行了表征。用合成的新分子(离子载体)制备的电位电极对铅(II)离子具有选择性。这种新型电极的检测下限为6.98 × 在1.0的宽浓度范围内为10-7M × 10–6–1.0 × 10-1米。实验数据表明,该电极具有良好的重复性、选择性和稳定性。同时,它可以在宽的pH范围内工作,而不受pH变化的影响。研究了所开发的电极的电位性能参数,并在不同的水样中进行了分析应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Chemical Papers
Chemical Papers 化学-化学综合
CiteScore
3.90
自引率
4.50%
发文量
590
审稿时长
2.5 months
期刊介绍: Chemical Papers is a peer-reviewed, international journal devoted to basic and applied chemical research. It has a broad scope covering the chemical sciences, but favors interdisciplinary research and studies that bring chemistry together with other disciplines.
期刊最新文献
Leaching studies of magnesite using perchloric acid thermochemical and electrochemical treatment of magnesium chloride A unique synthesis of N-(Z)-5-bromo-6-hydroxyhexahydro isobenzofuran-1(3H)-ylidene)methanaminium bromide Synthesis and characterization of related compounds of Bisoprolol fumarate: a β-blocker agent Determination of sodium bicarbonate in compositions of smoke-type fireworks based on automatic potentiometric setting dynamic pH titration method Synthesis of amino acid-functionalized Cit-T20-GNPs and investigation of their metal ion selectivity for colorimetric sensing
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1