Effect of square pulse current densities on anticorrosive behavior of Ni–Zn multilayer deposited coatings on mild steel

IF 2.1 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Chemical Papers Pub Date : 2023-07-26 DOI:10.1007/s11696-023-02986-y
Akshatha R. Shetty, A. Chitharanjan Hegde
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Abstract

This paper reports the production of Ni–Zn multilayer alloy coating to improve the anticorrosive behavior of the mild steel material. The deposition technique follows the square wave current pulse technique. Initially, the effect of current densities on the anticorrosive behavior of the Ni–Zn was investigated. Later, the current densities were optimized in different combinations to get a multilayer of Ni–Zn with different degrees of layering. The Ni–Zn multilayer coatings were developed on the surface of mild steel with different numbers of layers by square pulsing current density of 1 Adm−2 and 3 Adm−2. The deposited Ni–Zn alloy coating was studied for its electrochemical behavior toward corrosion. Results revealed that the anticorrosive behavior of the multilayer Ni–Zn alloy coating was found to be many folds higher than that of monolayer Ni–Zn alloy coating. The comparison study of corrosion data revealed that (Ni–Zn)1/3/300 multilayer coatings are less prone to undergo corrosion among all developed monolayer and multilayer coatings. The corrosion rate of (Ni–Zn)1/3/300 was found to be less and in the range of 0.37 mm year−1 among all developed coatings.

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方脉冲电流密度对低碳钢Ni–Zn多层镀层防腐性能的影响
本文报道了生产镍-锌多层合金涂层以改善低碳钢材料的防腐性能。沉积技术遵循方波电流脉冲技术。首先,研究了电流密度对Ni–Zn防腐性能的影响。随后,以不同的组合优化电流密度,以获得具有不同分层程度的Ni–Zn多层。通过1Adm−2和3Adm−2的方形脉冲电流密度,在不同层数的软钢表面形成了Ni–Zn多层涂层。研究了沉积的镍锌合金镀层的电化学腐蚀行为。结果表明,多层镍锌合金涂层的防腐性能比单层镍锌合金镀层高出许多倍。腐蚀数据的比较研究表明,在所有开发的单层和多层涂层中,(Ni–Zn)1/3/300多层涂层不太容易发生腐蚀。在所有开发的涂层中,(Ni–Zn)1/300的腐蚀速率较小,在0.37 mm年-1的范围内。
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来源期刊
Chemical Papers
Chemical Papers 化学-化学综合
CiteScore
3.90
自引率
4.50%
发文量
590
审稿时长
2.5 months
期刊介绍: Chemical Papers is a peer-reviewed, international journal devoted to basic and applied chemical research. It has a broad scope covering the chemical sciences, but favors interdisciplinary research and studies that bring chemistry together with other disciplines.
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