N. Denman, A. M. Emel’yanenko, O. A. Serenko, L. B. Boinovich
{"title":"Characterization of Superhydrophobic Coatings Based on PDMS and MQ Resin on Textured Surfaces","authors":"N. Denman, A. M. Emel’yanenko, O. A. Serenko, L. B. Boinovich","doi":"10.1134/S1061933X23600483","DOIUrl":null,"url":null,"abstract":"<p>The paper presents the results of studying coatings based on poly(dimethylsiloxane) rubber cross-linked with MQ resin at different contents of the latter. The PDMS : MQ resin ratios have been taken to be 2 : 1, 1 : 1, and 1 : 2. It has been shown that the application of a hydrophobic fluorinated-group-free composite with composition PDMS : MQ = 1 : 1 onto a pre-textured surface by spin-coating or deep-coating results in the formation of superhydrophobic coatings. The coatings are characterized by extremely large contact angles (170°) and rolling angles no larger than 4°. The analysis of variations in the contact angle, surface tension, and contact diameter and volume of a water droplet that has been in contact with a coating for a long time has indicated a high hydrolytic resistance of the obtained coatings.</p>","PeriodicalId":521,"journal":{"name":"Colloid Journal","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2023-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloid Journal","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1061933X23600483","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The paper presents the results of studying coatings based on poly(dimethylsiloxane) rubber cross-linked with MQ resin at different contents of the latter. The PDMS : MQ resin ratios have been taken to be 2 : 1, 1 : 1, and 1 : 2. It has been shown that the application of a hydrophobic fluorinated-group-free composite with composition PDMS : MQ = 1 : 1 onto a pre-textured surface by spin-coating or deep-coating results in the formation of superhydrophobic coatings. The coatings are characterized by extremely large contact angles (170°) and rolling angles no larger than 4°. The analysis of variations in the contact angle, surface tension, and contact diameter and volume of a water droplet that has been in contact with a coating for a long time has indicated a high hydrolytic resistance of the obtained coatings.
期刊介绍:
Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.