Characterization of Superhydrophobic Coatings Based on PDMS and MQ Resin on Textured Surfaces

IF 1.4 4区 化学 Q4 CHEMISTRY, PHYSICAL Colloid Journal Pub Date : 2023-10-04 DOI:10.1134/S1061933X23600483
N. Denman, A. M. Emel’yanenko, O. A. Serenko, L. B. Boinovich
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Abstract

The paper presents the results of studying coatings based on poly(dimethylsiloxane) rubber cross-linked with MQ resin at different contents of the latter. The PDMS : MQ resin ratios have been taken to be 2 : 1, 1 : 1, and 1 : 2. It has been shown that the application of a hydrophobic fluorinated-group-free composite with composition PDMS : MQ = 1 : 1 onto a pre-textured surface by spin-coating or deep-coating results in the formation of superhydrophobic coatings. The coatings are characterized by extremely large contact angles (170°) and rolling angles no larger than 4°. The analysis of variations in the contact angle, surface tension, and contact diameter and volume of a water droplet that has been in contact with a coating for a long time has indicated a high hydrolytic resistance of the obtained coatings.

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基于PDMS和MQ树脂的纹理表面超疏水涂层的表征
本文介绍了以MQ树脂交联的聚二甲基硅氧烷橡胶为基体,在MQ树脂含量不同的情况下对涂料进行研究的结果。PDMS:MQ树脂的比例取为2∶1、1∶1和1∶2。已经表明,通过旋涂或深涂将组成为PDMS:MK=1∶1的疏水性氟化无基团复合物应用到预织构表面上导致形成超疏水涂层。涂层的特点是接触角非常大(170°),滚动角不大于4°。对与涂层长时间接触的水滴的接触角、表面张力、接触直径和体积的变化的分析表明,所获得的涂层具有高的耐水解性。
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来源期刊
Colloid Journal
Colloid Journal 化学-物理化学
CiteScore
2.20
自引率
18.20%
发文量
36
审稿时长
6-12 weeks
期刊介绍: Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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