Application of Bio-Profiles of Chemical Reactions for Analysis of Solvent Impact on Overall Toxicity of C–C Cross-Coupling Process

IF 0.8 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Doklady Chemistry Pub Date : 2022-11-03 DOI:10.1134/S0012500822600080
K. S. Egorova, A. S. Galushko, L. U. Dzhemileva, V. A. D’yakonov,  V. P. Ananikov
{"title":"Application of Bio-Profiles of Chemical Reactions for Analysis of Solvent Impact on Overall Toxicity of C–C Cross-Coupling Process","authors":"K. S. Egorova,&nbsp;A. S. Galushko,&nbsp;L. U. Dzhemileva,&nbsp;V. A. D’yakonov,&nbsp; V. P. Ananikov","doi":"10.1134/S0012500822600080","DOIUrl":null,"url":null,"abstract":"<p>In this work, we used a recently proposed concept of bio-Profiles and bio-Factors for studying the solvent contribution into the “overall cytotoxicity” of chemical reactions by the example of synthesis of 1,1'-biphenyl from aryl halide and phenylboronic acid. Two standard solvents (ethanol and <i>N</i>-methylpyrrolidone) and four ionic liquids (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, and cholinium bis(trifluoromethylsulfonyl)imide) were analyzed.</p>","PeriodicalId":530,"journal":{"name":"Doklady Chemistry","volume":"504 2","pages":"106 - 117"},"PeriodicalIF":0.8000,"publicationDate":"2022-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Doklady Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0012500822600080","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

In this work, we used a recently proposed concept of bio-Profiles and bio-Factors for studying the solvent contribution into the “overall cytotoxicity” of chemical reactions by the example of synthesis of 1,1'-biphenyl from aryl halide and phenylboronic acid. Two standard solvents (ethanol and N-methylpyrrolidone) and four ionic liquids (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, and cholinium bis(trifluoromethylsulfonyl)imide) were analyzed.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
化学反应生物谱在溶剂对C-C交联过程总毒性影响分析中的应用
在这项工作中,我们采用了最近提出的生物概况和生物因子的概念,以芳基卤化物和苯硼酸合成1,1'-联苯为例,研究了化学反应中溶剂对“整体细胞毒性”的贡献。分析了两种标准溶剂(乙醇和n -甲基吡咯烷酮)和四种离子液体(1-乙基-3-甲基咪唑二(三氟甲基磺酰基)亚胺、1-乙基-3-甲基咪唑四氟硼酸盐、1-丁基-3-甲基咪唑二(三氟甲基磺酰基)亚胺和胆碱二(三氟甲基磺酰基)亚胺)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Doklady Chemistry
Doklady Chemistry 化学-化学综合
CiteScore
1.20
自引率
12.50%
发文量
7
审稿时长
6-12 weeks
期刊介绍: Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.
期刊最新文献
Synthesis of Polyfunctional O-Containing Compounds with Acetal Fragment by Low-Temperature Ozonolysis of 1,3-Dioxepins Doped Silicon Nanoparticles. A Review Evaluation of Toxicity of Ionic Liquids as Solvents in C–C Cross-coupling Reaction Antifriction Composites Based on a Two-Component Modified Phenol–Formaldehyde Binder Synthesis of Novel Composite Sorbents Based on Titanium, Calcium, and Magnesium Phosphates
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1