Understanding the effects of ionic liquids and antisolvent addition on the extraction and recovery of Pinus radiata bark components

IF 1.7 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Journal of Wood Chemistry and Technology Pub Date : 2022-06-24 DOI:10.1080/02773813.2022.2088793
N. Brar, W. Grigsby, S. Hill, L. Raymond, C. C. Weber
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Abstract

Abstract Ionic liquids (ILs) are being increasingly explored as extraction solvents due to their tunable properties, which can control their ability to dissolve an array of solutes. IL selection requires an in-depth understanding of the consequences of IL structure on extraction outcomes for different substrates. Here, 14 ILs containing cations and anions that have been systematically modified to examine key structural effects have been explored for the extraction of chemical components from Pinus radiata bark. The extraction efficiency relative to the mass of bark ranged from 4 to 70%, and the isolation of bark components was evaluated using antisolvent addition. Extraction outcomes highlighted the importance of the IL anion in affecting extraction efficiency and selectivity, with a secondary role from the IL cation, and point toward a simple route for improving the overall selectivity of biomass extractions through control of the antisolvent addition process.
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了解离子液体和抗溶剂添加对辐射松皮成分提取和回收的影响
离子液体(ILs)由于其可调节的性质,可以控制其溶解一系列溶质的能力,因此越来越多地被探索作为萃取溶剂。IL选择需要深入了解IL结构对不同底物提取结果的影响。本文对14种含有阳离子和阴离子的化学成分进行了系统修饰,研究了从辐射松树皮中提取化学成分的关键结构效应。相对于树皮质量的提取效率为4 ~ 70%,并通过添加抗溶剂对树皮成分的分离进行了评价。提取结果强调了IL阴离子在影响提取效率和选择性方面的重要性,并指出了通过控制抗溶剂加成过程来提高生物质提取整体选择性的简单途径。
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来源期刊
Journal of Wood Chemistry and Technology
Journal of Wood Chemistry and Technology 工程技术-材料科学:纸与木材
CiteScore
3.70
自引率
20.00%
发文量
37
审稿时长
3 months
期刊介绍: The Journal of Wood Chemistry and Technology (JWCT) is focused on the rapid publication of research advances in the chemistry of bio-based materials and products, including all aspects of wood-based polymers, chemicals, materials, and technology. JWCT provides an international forum for researchers and manufacturers working in wood-based biopolymers and chemicals, synthesis and characterization, as well as the chemistry of biomass conversion and utilization. JWCT primarily publishes original research papers and communications, and occasionally invited review articles and special issues. Special issues must summarize and analyze state-of-the-art developments within the field of biomass chemistry, or be in tribute to the career of a distinguished researcher. If you wish to suggest a special issue for the Journal, please email the Editor-in-Chief a detailed proposal that includes the topic, a list of potential contributors, and a time-line.
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