Organic Matter Characterization and Palynological Evidence of Mid-Ordovician to Pennsylvanian Age of the Tabenken Coal, Northwest Cameroon

Abimnui Norine Wendi, Njilah Isaac Konfor, Yongue Fouateu Rose, Bruno Ndicho Nfor
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Abstract

: In this work, we intend to investigate the kerogen composition of the Tabenken coal hence, its palaeo-depositional environment and age. Tabenken is one of the three areas in the continental sectors of the CVL (Cameroon Volcanic Line) where coal occurs in between a granitic basement and volcanic outpours. Samples of coal from this seam were studied to determine the organic matter richness, maturity, depositional environment and its age through organic geochemical techniques such as Rock-Eval pyrolysis and palynological studies. HI (Hydrogen Index) obtained is less than 200 mgHC/gTOC for most of the samples indicating Type III kerogen for these samples (gas prone) and terrestrial source of the original peat-forming organic matter. One sample presents a HI of 462 mgHC/gTOC indicating organic matter type II, prone to producing oil. Palynological studies reveal the presence of hydrogen-rich AOM (Amorphous Organic Matter) indicating preservation under dysoxic-anoxic conditions. High values of TOC ranging from 0.29 to 1.98 are suggestive of AOM of terrestrial origin. The remarkable absence of pollen suggestive of deposition before the Pennsylvanian during which the earliest forms of flowering plants first appeared displays a relative abundance of spores in the organic residue suggestive of deposition from the mid-Ordovician. Careful interpretation of palynological data suggests the coal was laid down from the mid-Ordovician to the Pennsylvanian age.
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喀麦隆西北部Tabenken煤中奥陶统至宾夕法尼亚期有机质特征及孢粉学证据
本文拟对大本肯煤的干酪根组成进行研究,从而确定其古沉积环境和沉积时代。Tabenken是喀麦隆火山线(CVL)大陆板块的三个地区之一,煤产于花岗岩基底和火山喷口之间。通过岩石热解、孢粉学等有机地球化学技术对该煤层煤样进行了有机质丰度、成熟度、沉积环境和年龄的研究。大多数样品的氢指数小于200 mgHC/gTOC,表明这些样品的干酪根类型为III型(气倾向),原始泥炭形成有机质为陆源。其中一个样品的HI为462 mgHC/gTOC,表明有机质类型为II型,具有产油倾向。孢粉学研究揭示了富氢AOM(无定形有机物)的存在,表明在缺氧-缺氧条件下保存。TOC值在0.29 ~ 1.98之间,表明AOM是陆源的。在宾夕法尼亚纪(开花植物最早出现的时期)之前,花粉的显著缺失表明,有机残留物中孢子的相对丰富表明中奥陶世的沉积。对孢粉学数据的仔细解读表明,这些煤是从中奥陶世到宾夕法尼亚时代沉积下来的。
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