High efficient solar photocatalytic carbon nanoparticles

Diego Flores-Oña, A. Fullana
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Abstract

In the present study, the photocatalytic activity of carbon nanoparticles (CNPs) in the degradation of methylene blue (MB) using sunlight was analyzed. The CNPs were synthesized by solvent-assisted hydrothermal carbonization (HTC) and were characterized by various spectroscopic techniques: TEM and SEM microscopy, UV-Vis, FTIR, Fluorescence, and XPS. By changing the conditions of the HTC process, the surface chemistry of CNPs was functionalized, thus a great quantity of oxygenated functional groups was generated, which eventually influenced the photocatalytic process. Next, tests were carried out with different types of nanoparticles, varying the concentration of the dye and the type of light used in the irradiation. As a result of this, more than 93% of MB degradation was achieved in 20 min of irradiation using sunlight. This result is promising since it has not been achieved by other nanomaterial. This research can be a potential starting point for the development of new solar photocatalysts.
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高效太阳能光催化碳纳米颗粒
在本研究中,分析了碳纳米颗粒(CNPs)在阳光下降解亚甲基蓝(MB)的光催化活性。通过溶剂辅助水热碳化(HTC)合成了CNPs,并通过各种光谱技术进行了表征:TEM和SEM显微镜、UV-Vis、FTIR、荧光和XPS。通过改变HTC过程的条件,CNPs的表面化学被功能化,从而产生大量的含氧官能团,最终影响了光催化过程。接下来,用不同类型的纳米颗粒进行测试,改变染料的浓度和照射中使用的光的类型。结果,在使用阳光的20分钟照射中实现了超过93%的MB降解。这一结果是有希望的,因为其他纳米材料还没有实现这一结果。这项研究可以成为开发新型太阳能光催化剂的潜在起点。
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