HYDROTHERMAL LIQUEFACTION OF MAHOGANY (Swietenia macrophylla) SAWDUST

Mulhidin Mulhidin, A. T. Yuliansyah, A. Prasetya
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Abstract

Hydrothermal treatment is one of the thermochemical methods to convert complex organic compounds, such as organic waste and biomass, into upgraded solid, bio-oil, and other dissolved chemicals by utilizing the properties of water at near critical condition. Such method is very potential since the process is environmentally friendly and the products have more added values. In this research, conversion of mahogany sawdust (Swietenia macrophylla) using hydrothermal treatment method was studied. The experiments were conducted in a batch autoclave with temperature range of 200-300oC and initial pressure of 1 MPa. At targeted temperature, the process was hold for 30 minutes. In addition, biomass-water ratio (B/W ratio) for experiments was varied at 1:20, 2:20 and 3:20. The liquid products, which were characterized by Gas chromatography-Mass spectrometry (GC/MS) instrument, showed the presence of furfural and several organic acids, but no flavonoid compounds. Thus, coloring potential test of hydrothermal liquid was unsuccessful; there were not any color attached on the cloth specimen. On the other hand, proximate and ultimate test results indicated that solid products had high heating value (HHV) of 4625.34-4876.25 cal/g which were comparable to that of sub-bituminous coal.
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红木木屑的水热液化
水热处理是利用水在接近临界条件下的特性,将复杂的有机化合物(如有机废物和生物质)转化为升级固体、生物油和其他溶解化学物质的热化学方法之一。该方法工艺环保,产品附加值高,具有很大的发展潜力。研究了水热法对红木木屑的转化。实验在温度范围为200-300℃,初始压力为1 MPa的间歇式高压灭菌器中进行。在目标温度下,该过程保持30分钟。另外,试验的生物量水比(B/W)分别为1:20、2:20和3:20。液相产物经气相色谱-质谱联用(GC/MS)表征,检测出糠醛和几种有机酸,但未发现类黄酮化合物。因此,热液显色电位测试不成功;布料样品上没有附着任何颜色。另一方面,近似和极限试验结果表明,固体产物具有较高的热值(HHV),为4625.34 ~ 4876.25 cal/g,与亚烟煤相当。
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