{"title":"CoIIIcorrole: versatile synthetic methods and wide range of applications","authors":"Tingting Gu, Zhen Zhang, Shengyu Zhang, Weihua Zhu, Xu Liang","doi":"10.1007/s10847-021-01127-w","DOIUrl":null,"url":null,"abstract":"<div><p>This review introduces the synthesis, properties and applications of Co<sup>III</sup>corroles. The synthesis methods are containing A<sub>2</sub>B type, A<sub>3</sub> type, ABC type, Hangman H<sub>3</sub>corrole and H<sub>3</sub>biscorrole synthesis and their metal-inserting reactions. Also, the spectroscopic and electrochemical properties of Co<sup>III</sup>corroles were also described. However, the most important part of this paper is about the application of Co<sup>III</sup>corroles, including the development of sustainable and pollution-free chemical energy sources, the degradation of environmentally harmful organochlorides, and the oxidation of alkanes.</p></div>","PeriodicalId":638,"journal":{"name":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","volume":"102 5-6","pages":"373 - 394"},"PeriodicalIF":2.3000,"publicationDate":"2022-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10847-021-01127-w","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Agricultural and Biological Sciences","Score":null,"Total":0}
引用次数: 0
Abstract
This review introduces the synthesis, properties and applications of CoIIIcorroles. The synthesis methods are containing A2B type, A3 type, ABC type, Hangman H3corrole and H3biscorrole synthesis and their metal-inserting reactions. Also, the spectroscopic and electrochemical properties of CoIIIcorroles were also described. However, the most important part of this paper is about the application of CoIIIcorroles, including the development of sustainable and pollution-free chemical energy sources, the degradation of environmentally harmful organochlorides, and the oxidation of alkanes.
期刊介绍:
The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites.
The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.