Correlation and prediction of solubility of hydrogen in alkenes and its dissolution properties

Abstract

In this work, solubility of hydrogen in some alkenes was investigated at different temperatures and pressures. Solubility values were calculated using the Peng–Robinson equation of state. Binary interaction parameters were calculated using fitting the equation of state on experimental data, Group contribution method and Moysan correlations and total average absolute deviation for these methods was 3.90, 17.60 and 13.62, respectively. Because hydrogen solubility in Alkenes is low, Henry’s law for these solutions were investigated, too. Results of calculation showed with increasing temperature, Henry’s constant was decreased. The temperature dependency of Henry’s constants of hydrogen in ethylene and propylene was higher than to other alkenes. In addition, using Van’t Hoff equation, the thermodynamic parameters for dissolution of hydrogen in various alkenes were calculated. Results indicated that the dissolution of hydrogen was spontaneous and endothermic. The total average of dissolution enthalpy (\({\Delta H}^{^\circ }\)) and Gibbs free energy (\({\Delta G}^{^\circ }\)) for these systems was 3.867?kJ/mol and 6.361?kJ/mol, respectively. But dissolution of hydrogen in almost of alkenes was not an entropy-driven process.