Priya Subramanian;Andrew J Archer;Edgar Knobloch;Alastair M Rucklidge
{"title":"Snaking without subcriticality: grain boundaries as non-topological defects","authors":"Priya Subramanian;Andrew J Archer;Edgar Knobloch;Alastair M Rucklidge","doi":"10.1093/imamat/hxab032","DOIUrl":null,"url":null,"abstract":"Non-topological defects in spatial patterns such as grain boundaries in crystalline materials arise from local variations of the pattern properties such as amplitude, wavelength and orientation. Such non-topological defects may be treated as spatially localized structures, i.e. as fronts connecting distinct periodic states. Using the two-dimensional quadratic-cubic Swift–Hohenberg equation, we obtain fully nonlinear equilibria containing grain boundaries that separate a patch of hexagons with one orientation (the grain) from an identical hexagonal state with a different orientation (the background). These grain boundaries take the form of closed curves with multiple penta-hepta defects that arise from local orientation mismatches between the two competing hexagonal structures. Multiple isolas occurring robustly over a wide range of parameters are obtained even in the absence of a unique Maxwell point, underlining the importance of retaining pinning when analysing patterns with defects, an effect omitted from the commonly used amplitude-phase description. Similar results are obtained for quasiperiodic structures in a two-scale phase-field model.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2021-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"100","ListUrlMain":"https://ieeexplore.ieee.org/document/9619538/","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 5
Abstract
Non-topological defects in spatial patterns such as grain boundaries in crystalline materials arise from local variations of the pattern properties such as amplitude, wavelength and orientation. Such non-topological defects may be treated as spatially localized structures, i.e. as fronts connecting distinct periodic states. Using the two-dimensional quadratic-cubic Swift–Hohenberg equation, we obtain fully nonlinear equilibria containing grain boundaries that separate a patch of hexagons with one orientation (the grain) from an identical hexagonal state with a different orientation (the background). These grain boundaries take the form of closed curves with multiple penta-hepta defects that arise from local orientation mismatches between the two competing hexagonal structures. Multiple isolas occurring robustly over a wide range of parameters are obtained even in the absence of a unique Maxwell point, underlining the importance of retaining pinning when analysing patterns with defects, an effect omitted from the commonly used amplitude-phase description. Similar results are obtained for quasiperiodic structures in a two-scale phase-field model.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.