Reconstructing formation processes at the Canary Islands indigenous site of Belmaco Cave (La Palma, Spain) through a multiproxy geoarchaeological approach

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-07-28 DOI:10.1002/gea.21972
Enrique Fernández-Palacios, Margarita Jambrina-Enríquez, Susan M. Mentzer, Caterina Rodríguez de Vera, Ada Dinckal, Natalia Égüez, Antonio V. Herrera-Herrera, Juan Francisco Navarro Mederos, Efraín Marrero Salas, Christopher E. Miller, Carolina Mallol
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引用次数: 2

Abstract

The indigenous populations of La Palma (Canary Islands), who arrived on the island from Northwest Africa ca. 2000 years B.P., were predominantly pastoralists. Yet, many aspects of their subsistence economy such as the procurement, management, and use of wild plant resources remain largely unknown. To explore this, we studied the 600–1100-year-old archaeological site of Belmaco Cave, which comprises a stratified sedimentary deposit representative of a fumier. Here, we present a high-resolution, multiproxy geoarchaeological study combining soil micromorphology, lipid biomarker analysis, X-ray diffraction, μ-X-ray diffraction, μ-X-ray fluorescence, Fourier transform infrared spectroscopy, and μ-Fourier transform infrared spectroscopy, to characterize formation processes and explore plant sources. Recurrent goat/sheep habitation and maintenance activities are represented by interstratified layers of unburned dung, charcoal-rich sediment, and dung ash. Lipid biomarker data show a herd diet mainly composed of herbaceous plants, which is key to understanding the mobility of indigenous shepherds. Our results also revealed an unusual suite of authigenic minerals including hazenite, aragonite, and sylvite, possibly formed through diagenetic processes involving interaction between ash, dung, urine, volcanogenic components, and bacterial activity, coupled with arid and alkaline conditions. Our study shows the potential of a multiproxy approach to a fumier deposit in a volcanogenic sedimentary context.

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通过多元地质考古方法重建加那利群岛Belmaco洞穴(西班牙拉帕尔马)土著遗址的形成过程
拉帕尔马(加那利群岛)的土著居民大约在公元前2000年从西北非洲来到该岛,主要是牧民。然而,它们生存经济的许多方面,如野生植物资源的采购、管理和使用,在很大程度上仍然未知。为了探索这一点,我们研究了有600–1100年历史的Belmaco洞穴考古遗址,该遗址包括一个代表烟化岩的层状沉积矿床。在这里,我们结合土壤微观形态、脂质生物标志物分析、X射线衍射、μ-X射线衍射、γ-X射线荧光、傅立叶变换红外光谱和μ傅里叶变换红外光谱,进行了一项高分辨率、多氧体的地质考古研究,以表征形成过程并探索植物来源。山羊/绵羊的栖息地和维护活动以未燃烧的粪便、富含木炭的沉积物和粪灰的层间层为代表。脂质生物标志物数据显示,羊群饮食主要由草本植物组成,这是了解土著牧羊人流动性的关键。我们的研究结果还揭示了一套不同寻常的自生矿物,包括霞石、文石和钾盐,可能是通过成岩过程形成的,包括灰烬、粪便、尿液、火山成分和细菌活性之间的相互作用,再加上干旱和碱性条件。我们的研究表明,在火山成因沉积背景下,对烟化矿床采用多氧方法的潜力。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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