M. D. Smolikov, V. A. Shkurenok, L. I. Bikmetova, N. N. Leont’eva, A. V. Lavrenov
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引用次数: 0
Abstract
The isomerization of heptane and hexane and their mixtures in the presence of Pt/WO3–ZrO2 catalysts with a tungsten oxide content of 10–35 wt % has been studied. It has been shown that the best parameters of the isomerization of a mixture of C6–C7 alkanes are achieved in the presence of catalysts containing 15–20 wt % WO3. According to temperature-programmed desorption of ammonia, this range of tungsten oxide content is characterized by an increase in the number of acid sites, which, according to IR spectroscopy of adsorbed CO molecules, occurs mostly due to an increase in the number of Brønsted acid sites.
期刊介绍：
The journal covers the following topical areas:
Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.
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