Synthesis and Application of Nanocomposite Reinforced with Decorated Multi Walled Carbon Nanotube with Luminescence Quantum Dots

J. A. Dalaeen, Yashfeen Khan, Anees Ahmad
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Abstract

Amidst the COVID-19 pandemic, environmental problems such as energy crisis, global warming, and contamination from pathogenic micro-organisms are still prevailed and strongly demanded progress in high-performance energy storing and anti-microbial materials. The nanocomposites are materials that have earned large interest owing to their promising applications for countering global issues related to sustainable energy and a flourishing environment. Here, polypyrrole coated hybrid nanocomposites of multi-walled carbon nanotube and cadmium sulfide quantum dots named MCP were synthesized using facile and low-cost in-situ oxidative polymerization method. Characterization techniques confirmed the synthesis. Electrochemical studies showed that the nanocomposite 1-MCP showed an impressively higher super capacitance behavior in comparison to f-MWCNT, 7-MCP and 5-MCP. The improved performance of the nanocomposites was attributed mainly to the good conductivity of carbon nanotubes and polypyrrole, high surface area, and stability of the carbon nanotubes and the high electrocatalytic activity of the cadmium sulfide quantum dots. Owing to the synergistic effect of MWCNT, CdS, and PPy the synthesized ternary nanocomposite also inhibited the growth and multiplication of tested bacteria such as S. aureus, and E. coli completely within 24 h. On the whole, the assimilated nanocomposite MCP opens promising aspects for the development of upcoming energy storage devices and as an antibacterial agent.
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发光量子点修饰多壁碳纳米管增强纳米复合材料的合成与应用
在新冠肺炎大流行期间,能源危机、全球变暖和病原微生物污染等环境问题仍然普遍存在,并强烈要求在高性能储能和抗菌材料方面取得进展。纳米复合材料因其在应对与可持续能源和繁荣环境相关的全球问题方面的良好应用而引起了人们的极大兴趣。采用简单、低成本的原位氧化聚合方法,合成了聚吡咯包覆的多壁碳纳米管和硫化镉量子点杂化纳米复合材料MCP。表征技术证实了该合成。电化学研究表明,与f-MWCNT、7-MCP和5-MCP相比,纳米复合材料1-MCP表现出令人印象深刻的更高的超电容行为。纳米复合材料性能的提高主要归因于碳纳米管和聚吡咯的良好导电性、碳纳米管的高表面积和稳定性以及硫化镉量子点的高电催化活性。由于MWCNT、CdS和PPy的协同作用,合成的三元纳米复合材料也在24小时内完全抑制了测试细菌(如金黄色葡萄球菌和大肠杆菌)的生长和增殖。总的来说,同化的纳米复合材料MCP为开发即将到来的储能器件和作为抗菌剂开辟了有前景的方面。
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