Adsorption of aqueous perfluorooctane sulfonate by raw and oleylamine-modified Iranian diatomite and zeolite: Material and application insight

Abstract

Perfluorooctanesulfonate (PFOS) is a hazardous chemical, and its presence in surface and groundwater poses a risk to environmental quality and human health. Containment is often applied to immobilize PFOS to stop or minimize the exposure. Mineral-based materials became promising adsorbents. However, there is scope to develop adsorbents using locally available minerals and understand their adsorption mechanisms. Here, we developed oleylamine-modified composites using naturally occurring Iranian zeolite and diatomaceous earth (DE). The mineralogy and surface properties of materials were fully characterized, and the adsorption of PFOS from simulated wastewater was linked to it. Clinoptilolite in zeolite sample, calcite and kaolinite in DE were main mineral assemblages. The raw samples also contained silica as a main constituent of them. Thermogravimetric analysis suggested that the materials were successfully modified with the oleylamine molecules in the material's structure and surfaces. These were further supported by scanning electronic microscopy (SEM), Fourier transmission infrared spectroscopy (FTIR), and surface and pore size analysis. After adsorption at various pHs, the isotherm of adsorption was also performed at ambient temperature. Modified DE and zeolite tend to adsorb PFOS (14.1 and 25.5 mg/g, respectively) more than their raw counterparts (4.72 and 0.39 mg/g, respectively). Adsorption models suggest monolayer and, in rare cases multilayer binding capacities and affinities toward PFOS. We analyzed the post-adsorption materials and discovered that electrostatic and hydrophobic interaction was likely the main cause of PFOS adsorbed to the material. This research helps to improve our knowledge of how PFOS adheres to untreated and surfactant-altered zeolite and DE in aquatic environments.