Kaoru Shomura, R. Mitsuhashi, M. Mikuriya, Y. Kataoka, M. Handa, H. Sakiyama
{"title":"Crystal Structure of a Mononuclear Iron(III) Complex, Hexakis(dimethylsulfoxide-κO)iron(III) Tris(hexafluoridophosphate)","authors":"Kaoru Shomura, R. Mitsuhashi, M. Mikuriya, Y. Kataoka, M. Handa, H. Sakiyama","doi":"10.2116/XRAYSTRUCT.35.31","DOIUrl":null,"url":null,"abstract":"X-ray method. The compound crystallized in the trigonal space group R 3 and Z = 3 with cell parameters a = 11.598(8)Å, c = 25.367(18)Å, V = 2955(4)Å 3 . The R 1 [ I > 2 σ ( I )] and wR 2 (all data) values were 0.0509 and 0.1565, respectively, for all 1630 independent reflections. The symmetry of the complex cation was found to belong to the S 6 point group, possessing a trigonally compressed octahedral coordination geometry with an O 6 donor set.","PeriodicalId":23922,"journal":{"name":"X-ray Structure Analysis Online","volume":" ","pages":""},"PeriodicalIF":0.1000,"publicationDate":"2019-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/XRAYSTRUCT.35.31","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0
Abstract
X-ray method. The compound crystallized in the trigonal space group R 3 and Z = 3 with cell parameters a = 11.598(8)Å, c = 25.367(18)Å, V = 2955(4)Å 3 . The R 1 [ I > 2 σ ( I )] and wR 2 (all data) values were 0.0509 and 0.1565, respectively, for all 1630 independent reflections. The symmetry of the complex cation was found to belong to the S 6 point group, possessing a trigonally compressed octahedral coordination geometry with an O 6 donor set.