Online monitoring of spatial-temporal distribution of harmful gases during advanced oxidation of NO by convolutional networks and gated recurrent units

IF 3 Q2 ENGINEERING, CHEMICAL Digital Chemical Engineering Pub Date : 2023-09-01 DOI:10.1016/j.dche.2023.100110
Yue Liu, Xiangxiang Gao, Zhongyu Hou
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Abstract

Online monitoring of the spatial-temporal distribution of harmful gases has always been a complex problem in the environmental field. This paper proposes a novel mathematical method for online monitoring of the spatial-temporal distribution of reactants by machine learning, which can help to remove harmful gases efficiently. In this model, we take the advanced oxidation of NO as an example to evaluate the model performance. The spatial features were extracted by CNN, and GRU extracted the temporal features in the sequence of spatial features. Five physical field variables (mass fraction of ozone, velocity, temperature, the wind direction of the horizontal plane, and the wind direction of the vertical plane) were put into the network to predict NO's spatial-temporal mass fraction distribution. Furthermore, the impact of sampling time interval on monitoring performance was also evaluated. The results show that both the instantaneous and continuous CFD (Computational Fluid Mechanics) and predicted values show high consistency, which indicates that the model can online monitor the spatial-temporal distribution of reactants successfully. In addition, the most suitable sampling time interval is 0.5 s, with low training error (RMSE=0.06 and nRMSE=0.3) and high relation coefficient (r=0.99), which shows the model has great perceived and predicted performance under this condition.

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卷积网络和门控递归单元在线监测NO深度氧化过程中有害气体的时空分布
有害气体时空分布的在线监测一直是环境领域的一个复杂问题。本文提出了一种利用机器学习在线监测反应物时空分布的数学方法,可以有效地去除有害气体。在该模型中,我们以NO的深度氧化为例来评价模型的性能。通过CNN提取空间特征,GRU在空间特征序列中提取时间特征。将5个物理场变量(臭氧质量分数、速度、温度、水平面风向和垂直风向)输入网络,预测NO的时空质量分数分布。此外,还评估了采样时间间隔对监测性能的影响。结果表明,瞬时和连续计算流体力学数值与预测值均具有较高的一致性,表明该模型能够成功地在线监测反应物的时空分布。此外,最合适的采样时间间隔为0.5 s,训练误差低(RMSE=0.06, nRMSE=0.3),相关系数高(r=0.99),表明该模型在该条件下具有良好的感知和预测性能。
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