3-D magnetic graphene balls as sorbents for cleaning oil spills

Abstract

A 3-D magnetic graphene ball (MGB) material was prepared using cellulose as the carbon source. Carbon-encapsulated iron nanoparticles (CEINs) were first prepared by hydrothermal carbonization of cellulose powder at 180°C. Then, the prepared CEINs were catalytically graphitized to graphene-encapsulated iron nanoparticles (GEINs) at 900°C. Finally, GEINs were treated in carbon dioxide at 700°C, during which the iron core was oxidized to magnetite (Fe3O4) nanoparticles, and graphene shells were peeled off from the iron cores to form graphene nanoplatelets. The graphene nanoplatelets consist of 1–10 layers graphene with the in-plane size of 20–30 nm. The prepared 3-D MGB was investigated for the removal of oil from water, which demonstrated outstanding adsorption performance and excellent recyclability.