Influence of inorganic additives on ash adhesion to a metal mesh during bamboo powder combustion

IF 1.7 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Journal of Wood Chemistry and Technology Pub Date : 2023-04-13 DOI:10.1080/02773813.2023.2198999
K. Tanoue, N. Umehara, M. Fujita, Y. Ninomiya
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Abstract

Abstract If the high melting point oxides added to the bamboo powder, the ash adhesion on the metal mesh during combustion was counterproductive in some cases, but effective in others. For SiO2 addition, although the shrinkage temperature (SHT) and part fusion temperature (PFT) were higher than that for only bamboo combustion due to the formed KAlSiO4 whose melting temperature was 1750 °C, the amount of ash on the metal mesh decreased in some cases or increased in others with the additive mass percentage of SiO2. Because there was the ratio distribution of K2O to SiO2 in the bamboo ash which decided the minimum melting point, the amount of adhered ash had a large variation. For CaO addition, although the SHT and PFT were higher than that for only bamboo combustion, whether ash deposition was enhanced or reduced could be determined by the distribution of char present in the combusted ash, resulting in the adhesion on the Inconel mesh. Because the ash for only bamboo combustion had 13.6% char, not only CaCO3 but also Ca(OH)2 with a lower melting point than that of CaO were formed during combustion. On the other hand, for MgO powder addition, as the ash formed that could be adhered by MgO particles was fluffy, the adhesion mass decreased with the additive mass percentage. Then all fusion temperatures of SHT, PFT, and the full fusion temperature (FFT) for MgO addition were higher than that for only bamboo combustion.
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无机添加剂对竹粉燃烧过程中灰分粘附金属网的影响
摘要在竹粉中加入高熔点氧化物,在燃烧过程中灰附着在金属网上,有时会产生反效果,但有时会产生效果。当SiO2加入时,由于形成的熔融温度为1750℃的KAlSiO4,虽然收缩温度(SHT)和部分熔合温度(PFT)高于纯竹燃烧,但随着SiO2添加量的增加,金属网上的灰分有所减少,也有所增加。由于竹灰中K2O与SiO2的比例分布决定了竹灰的最低熔点,因此竹灰的黏附量变化较大。添加CaO后,虽然SHT和PFT均高于竹材燃烧,但灰分沉积是增强还是减少,取决于燃烧后灰分中存在的焦炭的分布,从而导致灰分在Inconel网格上的粘附。由于竹材燃烧灰分含碳量为13.6%,燃烧过程中不仅会生成CaCO3,还会生成熔点低于CaO的Ca(OH)2。另一方面,对于MgO粉的添加,由于MgO颗粒可以粘附的灰分呈蓬松状,粘附质量随添加剂质量百分比的增加而降低。添加MgO的SHT、PFT和完全熔合温度(FFT)均高于竹材燃烧的熔合温度。
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来源期刊
Journal of Wood Chemistry and Technology
Journal of Wood Chemistry and Technology 工程技术-材料科学:纸与木材
CiteScore
3.70
自引率
20.00%
发文量
37
审稿时长
3 months
期刊介绍: The Journal of Wood Chemistry and Technology (JWCT) is focused on the rapid publication of research advances in the chemistry of bio-based materials and products, including all aspects of wood-based polymers, chemicals, materials, and technology. JWCT provides an international forum for researchers and manufacturers working in wood-based biopolymers and chemicals, synthesis and characterization, as well as the chemistry of biomass conversion and utilization. JWCT primarily publishes original research papers and communications, and occasionally invited review articles and special issues. Special issues must summarize and analyze state-of-the-art developments within the field of biomass chemistry, or be in tribute to the career of a distinguished researcher. If you wish to suggest a special issue for the Journal, please email the Editor-in-Chief a detailed proposal that includes the topic, a list of potential contributors, and a time-line.
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