Sustainable flame retardant treatment for cotton fabric using non formaldehyde cross linking agent

IF 0.6 Q3 ENGINEERING, MULTIDISCIPLINARY Mehran University Research Journal of Engineering and Technology Pub Date : 2023-01-01 DOI:10.22581/muet1982.2301.06
Saima Brohi, Ariba Shaikh, Iqra Jameel, M. Hamza, A. Memon, Iftikhar Ali Sahito, N. Mengal
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Abstract

Most flame-retardant finishing agents have been found to have an adverse effect on our environment and human skin because of the carcinogenic chemicals in their structure. Pyrovatex CP New is an Organophosphorus based flame retardant (FR) agent widely used in FR treatment of combustible. However, the main problem related to it is the release of high formaldehyde content (a known carcinogen). When used with methylated melamine (MM) an effective cross-linker. The objective of this research was to use citric acid (CA) and its integration with sodium hypophosphite (NaH2PO2) and two different co-catalyst Titanium dioxide (TiO2) and phosphoric acid (PA) as a flame‐retardant finishing for cotton fabrics. The flammability of cotton fabric was assessed by a manual vertical flammability test, it is found that the combination of co-catalysts in FR formulation lowers the flammability of cotton. The pyrolysis characteristics and char residue yield of the treated cotton shows that the flame retardancy improves as the amount of catalyst is increased. The whiteness index, crease recovery and tensile strength of the treated cotton fabric was also significantly improved with our suggested recipe formulation. The finished cotton has significant variations in terms of its tensile strength, crease recovery, and whiteness index.
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无醛交联剂对棉织物的可持续阻燃处理
大多数阻燃整理剂由于其结构中含有致癌化学物质,已被发现对我们的环境和人类皮肤有不利影响。PyrogatexCP-New是一种广泛用于可燃物阻燃处理的有机磷系阻燃剂。然而,与之相关的主要问题是甲醛含量高(一种已知的致癌物)的释放。当与甲基化三聚氰胺(MM)一起使用时,它是一种有效的交联剂。本研究的目的是使用柠檬酸(CA)及其与次磷酸钠(NaH2PO2)和两种不同的助催化剂二氧化钛(TiO2)和磷酸(PA)作为棉织物的阻燃整理剂。通过手动垂直燃烧试验对棉织物的燃烧性能进行了评估,发现FR配方中的助催化剂组合降低了棉花的燃烧性能。处理后的棉花的热解特性和残炭产率表明,随着催化剂用量的增加,阻燃性提高。采用我们提出的配方,处理后的棉织物的白度指数、折皱回复率和抗拉强度也得到了显著提高。成品棉在抗拉强度、折皱恢复率和白度指数方面存在显著差异。
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自引率
0.00%
发文量
76
审稿时长
40 weeks
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