Two Different Compounds in One Crystal: di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II)
{"title":"Two Different Compounds in One Crystal: di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II)","authors":"Isabelle Sasaki, Sonia Mallet-Ladeira","doi":"10.1007/s10870-022-00970-0","DOIUrl":null,"url":null,"abstract":"<div><p>The crystal structures of di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)] diplatinum(II) <b>(1)</b> and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II) <b>(2)</b> have been determined by means of the X-ray diffraction. Both complexes cocrystallize in the monoclinic space group C2/c with <i>a</i> = 39.5457(18) Å, <i>b</i> = 7.2482(4) Å, <i>c</i> = 21.2269(10) Å and β = 121.460(2)°. The asymmetric unit consists of half a centrosymmetric compound (complex <b>1</b>) and one full independent compound (complex <b>2</b>).</p><h3>Graphical Abstract</h3><p>The X-ray structures of co-crystallized di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) <b>(1)</b> as starting material and of the derivative chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II) <b>(2)</b> are reported.</p>\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\n </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"293 - 298"},"PeriodicalIF":0.4000,"publicationDate":"2022-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10870-022-00970-0.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Crystallography","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10870-022-00970-0","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
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Abstract
The crystal structures of di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)] diplatinum(II) (1) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II) (2) have been determined by means of the X-ray diffraction. Both complexes cocrystallize in the monoclinic space group C2/c with a = 39.5457(18) Å, b = 7.2482(4) Å, c = 21.2269(10) Å and β = 121.460(2)°. The asymmetric unit consists of half a centrosymmetric compound (complex 1) and one full independent compound (complex 2).
Graphical Abstract
The X-ray structures of co-crystallized di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) (1) as starting material and of the derivative chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II) (2) are reported.
通过 X 射线衍射测定了二μ-氯双[2-(5-甲基吡啶-2-基-κN)苯基-κC(1)]铂(II)(1)和氯(N,N-二甲基甲酰胺-κO)[2-(5-甲基吡啶-2-基-κN)苯基-κC(1)]铂(II)(2)的晶体结构。这两种复合物均在单斜空间群 C2/c 中共晶，a=39.5457(18)埃，b=7.2482(4)埃，c=21.2269(10)埃，β=121.460(2)°。不对称单元由半个中心对称化合物（复合物 1）和一个完整的独立化合物（复合物 2）组成。图解摘要 报告了共晶体化的二-μ-氯双[2-(5-甲基吡啶-2-基-κN)苯基-κC(1)]二铂(II)(1)的起始材料和衍生物氯(N,N-二甲基甲酰胺-κO)[2-(5-甲基吡啶-2-基-κN)苯基-κC(1)]铂(II)(2)的 X 射线结构。
期刊介绍：
Journal of Chemical Crystallography is an international and interdisciplinary publication dedicated to the rapid dissemination of research results in the general areas of crystallography and spectroscopy. Timely research reports detail topics in crystal chemistry and physics and their relation to problems of molecular structure; structural studies of solids, liquids, gases, and solutions involving spectroscopic, spectrometric, X-ray, and electron and neutron diffraction; and theoretical studies.
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