Study of Sonocatalytic Activity ZnO-WO3 Composite on Degradation Phenol in Aqueous Solution

N. Hindryawati, G. P. Maniam, Irvan Resi Pratama, R. Gunawan, S. Koesnarpadi
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引用次数: 1

Abstract

Sonocatalysis was used to study phenol degradation using a ZnO/WO3 composite. The degradation was assisted by ultrasonic waves at 40 KHz and conducted using the sonocatalysis technique. The degradation percentage was calculated using data from the UV-Vis spectrophotometer. The composite characterization results showed that the samples containing WO3, ZnO and also contained a new structure ZnWO4. The morphological length and width of the composites were revealed by SEM examination. Furthermore, heterogeneous particle sizes were discovered. The surface area of composite was bigger than before combined. The optimum condition in degradation of phenol by ZnO-WO3 composite are 0,4 g of catalyst at 30 ppm of phenol, 7 min reaction time with the greatest phenol degradation at 92,5%. The catalyst can be reused 5 times to degrade phenol at 85%. The composite catalyst and assisted with ultrasonic as the sonocatalytic technique are one of the most environmentally and cost effective.
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ZnO-WO3复合材料降解水中苯酚的声催化活性研究
采用声催化法研究了ZnO/WO3复合材料对苯酚的降解作用。在40 KHz的超声波辅助下,利用声催化技术进行降解。利用紫外可见分光光度计的数据计算降解率。复合表征结果表明,样品中含有WO3、ZnO,同时还含有一种新的结构ZnWO4。通过扫描电镜分析了复合材料的形态长度和宽度。此外,还发现了不均匀的颗粒尺寸。复合材料的表面积比复合前大。ZnO-WO3复合材料降解苯酚的最佳条件为:催化剂用量0.4 g,苯酚用量30 ppm,反应时间7 min,苯酚的最大降解率为92.5%。催化剂可重复使用5次,苯酚降解率达85%。复合催化剂和超声辅助催化技术是目前最环保、最经济的声催化技术之一。
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