Synthesis and characterization of resol type phenol-formaldehyde resin improved by SiO2-Np

IF 0.9 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Wood Research Pub Date : 2021-03-08 DOI:10.37763/WR.1336-4561/66.1.161169
G. Özbay, Erkan Sami Kokten, A. Özçifçi
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引用次数: 3

Abstract

In this work, resol type phenol–formaldehyde (RPF) resin was modified with silicon dioxide nanoparticles (SiO2-Np). SiO2-Np was added at varying ratios from 1 to 4 wt.% to improve the bonding performance of the RPF resins. The physical characteristics of the nano-modified RPF (nano-RPF) resins were examined. The effects of modification were studied by Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA). The results of FT-IR revealed that the nano-RPF resins were successfully produced by phenol, formaldehyde, and SiO2-Np. The nano-RPF resins demonstrated high thermal stability at temperatures above 500°C. The adhesive performance of the nano-RPF resins was investigated under dry and wet conditions. The nano-RPF resins indicated better adhesive performance than unmodified RPF resin. The RPF resin could be improved by SiO2-Np.
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SiO2-Np改性甲阶酚醛树脂的合成与表征
本文用二氧化硅纳米粒子(SiO2-Np)对甲阶酚醛树脂(RPF)进行了改性。以1至4wt%的不同比例添加SiO2-Np以改善RPF树脂的结合性能。考察了纳米改性RPF树脂的物理性能。通过傅立叶变换红外光谱(FT-IR)和热重分析(TGA)研究了改性效果。FT-IR结果表明,以苯酚、甲醛和SiO2-Np为原料成功制备了纳米RPF树脂。纳米RPF树脂在500°C以上的温度下表现出较高的热稳定性。研究了纳米RPF树脂在干燥和潮湿条件下的粘接性能。纳米RPF树脂显示出比未改性RPF树脂更好的粘合性能。SiO2-Np可以改善RPF树脂的性能。
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来源期刊
Wood Research
Wood Research 工程技术-材料科学:纸与木材
CiteScore
2.40
自引率
15.40%
发文量
81
审稿时长
5.4 months
期刊介绍: Wood Research publishes original papers aimed at recent advances in all branches of wood science (biology, chemistry, wood physics and mechanics, mechanical and chemical processing etc.). Submission of the manuscript implies that it has not been published before and it is not under consideration for publication elsewhere.
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