{"title":"Ligand-enabled C–H borylation of diverse classes of arenes","authors":"Md Emdadul Hoque , Sayan Dey , Mirja Md Mahamudul Hassan , Jagriti Chaturvedi , Saikat Guria , Jaitri Das , Brindaban Roy , Buddhadeb Chattopadhyay","doi":"10.1016/j.tchem.2022.100028","DOIUrl":null,"url":null,"abstract":"<div><p>Here we report a new 6,6′-bipyridine based ligand framework for the iridium-catalysed regioselective ortho borylation of diverse classes of arenes containing different functional groups. Moreover the developed method is highly selective for the directed C(sp (Altus and Love, 2021) [3]-H borylation of the 2-pyridyl amines as well as benzyl and homobenzyl amides directed by pyridine group and amide directed borylation of N-adjacent C–H bond of amides.</p></div>","PeriodicalId":74918,"journal":{"name":"Tetrahedron chem","volume":"3 ","pages":"Article 100028"},"PeriodicalIF":0.0000,"publicationDate":"2022-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666951X22000249/pdfft?md5=8c3b39ad17b803a63b9425471c7d1b9b&pid=1-s2.0-S2666951X22000249-main.pdf","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron chem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666951X22000249","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
Here we report a new 6,6′-bipyridine based ligand framework for the iridium-catalysed regioselective ortho borylation of diverse classes of arenes containing different functional groups. Moreover the developed method is highly selective for the directed C(sp (Altus and Love, 2021) [3]-H borylation of the 2-pyridyl amines as well as benzyl and homobenzyl amides directed by pyridine group and amide directed borylation of N-adjacent C–H bond of amides.
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