Electrochemical impedance spectroscopy studies of the buffered and non-buffered microbial fuel cell

IF 2.6 4区 工程技术 Q3 ELECTROCHEMISTRY Fuel Cells Pub Date : 2023-01-29 DOI:10.1002/fuce.202200088
Fatemeh Nourbakhsh PhD, Mohsen Mohsennia PhD, Mohammad Pazouki PhD
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Abstract

The positive effect of buffers to maintain a sui pH for microorganism growth and increase the electrolyte conductivity in microbial fuel cells (MFCs) encourages more studies on the development of new buffer solutions. The effect of types of biological buffers such as phosphate, tris, succinate, and maleate on power production in dual chamber MFC inoculated by saccharomyces cerevisiae has been examined. Electrochemical impedance spectroscopy has been used for evaluating the performance of the buffered and non-buffered MFC systems. Considering the important impact of buffer type on the resistance of ion migration within the electrolyte and electron transport resistance of the cell components, the internal resistance of the MFC with different used buffers has been obtained and compared. According to the obtained results, the tris buffer solution showed a positive influence on the power output with a power density of 25.41% higher than phosphate.

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缓冲和非缓冲微生物燃料电池的电化学阻抗谱研究
缓冲液对维持微生物生长的适宜pH值和提高微生物燃料电池(MFC)中电解质电导率的积极作用鼓励了对开发新缓冲溶液的更多研究。研究了磷酸盐、三酸盐、琥珀酸盐和马来酸盐等生物缓冲液对酿酒酵母接种的双室MFC发电的影响。电化学阻抗谱已用于评估缓冲和非缓冲MFC系统的性能。考虑到缓冲液类型对电解质内离子迁移阻力和电池组件的电子传输阻力的重要影响,获得并比较了不同缓冲液的MFC内阻。根据获得的结果,tris缓冲溶液对功率输出表现出积极影响,功率密度比磷酸盐高25.41%。
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来源期刊
Fuel Cells
Fuel Cells 工程技术-电化学
CiteScore
5.80
自引率
3.60%
发文量
31
审稿时长
3.7 months
期刊介绍: This journal is only available online from 2011 onwards. Fuel Cells — From Fundamentals to Systems publishes on all aspects of fuel cells, ranging from their molecular basis to their applications in systems such as power plants, road vehicles and power sources in portables. Fuel Cells is a platform for scientific exchange in a diverse interdisciplinary field. All related work in -chemistry- materials science- physics- chemical engineering- electrical engineering- mechanical engineering- is included. Fuel Cells—From Fundamentals to Systems has an International Editorial Board and Editorial Advisory Board, with each Editor being a renowned expert representing a key discipline in the field from either a distinguished academic institution or one of the globally leading companies. Fuel Cells—From Fundamentals to Systems is designed to meet the needs of scientists and engineers who are actively working in the field. Until now, information on materials, stack technology and system approaches has been dispersed over a number of traditional scientific journals dedicated to classical disciplines such as electrochemistry, materials science or power technology. Fuel Cells—From Fundamentals to Systems concentrates on the publication of peer-reviewed original research papers and reviews.
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