Optimization of lanthanum extraction in asymmetric rotation pilot plant column by using central composite methodology

Abstract

ABSTRACT The present work aimed to optimize the lanthanum extraction efficiency in the pilot-scale asymmetric rotating disc contactor. Optimal batch-scale extraction conditions were determined for the preparation of feed for extraction column (D2EHPA 0.08 mol/L; pH~8). In continuous mode, the optimization with the central composite design approach was performed by using three main parameters, such as continuous phase flow rate, agitation intensity, dispersed phase flow rate. Three responses studied were slip velocity, dispersed phase holdup, and extraction efficiency. The higher value of extraction efficiency for lanthanum extraction shows the main effect of agitation intensity on the dispersed phase holdup, slip velocity, and rate of mass transfer. The optimum conditions for extraction efficiency equal 98.5% were obtained at a rotation speed equal to 7.75 1/s, and phase flow rates equal to 1.25 × 10−5 m3/s. The new correlations are estimated to describe the holdup of the dispersed phase and the slip velocity with high accuracy and R-square values equal to 0.9734 and 0.9670, respectively. The results showed that the pilot plant asymmetric rotating disc column could be used as an appropriate column for the lanthanum extraction from aqueous solution as an example of rare earth metals.