Synthesis of 1,2,3-Triazole Derivatives and Its Evaluation as Corrosion Inhibitors for Carbon Steel

IF 2.3 Q3 ELECTROCHEMISTRY International journal of electrochemistry Pub Date : 2019-01-22 DOI:10.1155/2019/6759478
Gabriel O. Resende, S. Teixeira,, I. F. Figueiredo, Alexandre A. Godoy, Dafne Júlia F. Lougon, B. Cotrim, F. C. Souza
{"title":"Synthesis of 1,2,3-Triazole Derivatives and Its Evaluation as Corrosion Inhibitors for Carbon Steel","authors":"Gabriel O. Resende, S. Teixeira,, I. F. Figueiredo, Alexandre A. Godoy, Dafne Júlia F. Lougon, B. Cotrim, F. C. Souza","doi":"10.1155/2019/6759478","DOIUrl":null,"url":null,"abstract":"Heterocyclic compounds containing the 1,2,3-triazole moiety can be synthesized through click-chemistry, which is rapid reactions with good yields allowing the synthesis of great derivatives diversity by making minor changes in the reagents. The products were obtained with good yields through a synthetic route which uses ready available nonexpensive commercial reagents and without any further purification of any product or intermediate. The carbon steel anticorrosive activity was tested through weight loss and electrochemical assays in acid media. It was observed relevant inhibition efficiency (> 90%) for inhibitors 1 and 2. From Langmuir isotherm, it was hypothesized the adsorption of inhibitors on the carbon steel surface might occur by physical and chemical interaction; however, the activation energy raised suggests a physisorption process for the interaction of the inhibitor on the carbon steel surface.","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":" ","pages":""},"PeriodicalIF":2.3000,"publicationDate":"2019-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/6759478","citationCount":"11","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International journal of electrochemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2019/6759478","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 11

Abstract

Heterocyclic compounds containing the 1,2,3-triazole moiety can be synthesized through click-chemistry, which is rapid reactions with good yields allowing the synthesis of great derivatives diversity by making minor changes in the reagents. The products were obtained with good yields through a synthetic route which uses ready available nonexpensive commercial reagents and without any further purification of any product or intermediate. The carbon steel anticorrosive activity was tested through weight loss and electrochemical assays in acid media. It was observed relevant inhibition efficiency (> 90%) for inhibitors 1 and 2. From Langmuir isotherm, it was hypothesized the adsorption of inhibitors on the carbon steel surface might occur by physical and chemical interaction; however, the activation energy raised suggests a physisorption process for the interaction of the inhibitor on the carbon steel surface.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
1,2,3-三唑衍生物的合成及其对碳钢缓蚀剂的评价
含有1,2,3-三唑的杂环化合物可以通过点击化学合成,这是一种快速、产率高的反应,只需改变少量试剂,就可以合成多种多样的衍生物。该合成路线使用现成的廉价商业试剂,无需进一步提纯任何产品或中间体,产品收率高。用失重法和电化学法测定了碳钢在酸性介质中的防腐性能。观察到抑制剂1和2的抑制率为90%。从Langmuir等温线推测,缓蚀剂在碳钢表面的吸附可能是通过物理和化学相互作用发生的;然而,活化能的提高表明缓蚀剂在碳钢表面的相互作用是一个物理吸附过程。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
0.00%
发文量
2
审稿时长
7 weeks
期刊最新文献
Effect of Surface Composition on Electrochemical Oxidation Reaction of Carbon Monoxide and Ethanol of PtxRh1−x Solid Solution Electrodes Development and Characterization of a New Solid Polymer Electrolyte for Supercapacitor Device Size-Dependent Chlorinated Nitrogen-Doped Carbon Nanotubes: Their Use as Electrochemical Detectors for Catechol and Resorcinol Enabling the Electrochemical Performance of Maricite-NaMnPO4 and Maricite-NaFePO4 Cathode Materials in Sodium-Ion Batteries Electrooxidation and Development of a Highly Sensitive Electrochemical Probe for Trace Determination of the Steroid 11-Desoxycorticosterone Drug Residues in Water
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1