Analysis of reaction degree and factors of alkali-activated fly ash/slag

IF 1.8 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Magazine of Concrete Research Pub Date : 2023-03-03 DOI:10.1680/jmacr.22.00170
Bowen Wang, Yang Liu, Dong Luo, Yiwei Yang, Dunwen Huang, Hui Peng
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Abstract

This paper investigates the dissolution rates of alkali-activated fly ash and alkali-activated slag in hydrochloric acid(HCl) with various pH values. XRF, XRD, and FTIR were used to analyze the HCl-insoluble matter of alkali-activated fly ash and alkali-activated slag. The geopolymerization reaction degree of alkali-activated fly ash/slag can be determined based on the content of HCl-insoluble matter. The acid dissolution tests of alkali-activated fly ash/slag show that adding slag increases the geopolymerization degree of fly ash in most cases. With a certain slag content, the reaction degree of fly ash decreases with the increase of activator modulus and increases with the liquid/solid ratio. The increase of the activator concentration has a more pronounced effect when the slag content is low. At low activator concentration, the reaction degree of fly ash increases with the increase of slag content. The slag content corresponding to the highest reaction degree of fly ash is gradually reduced with the increased activator concentration.
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碱活性粉煤灰/矿渣反应程度及影响因素分析
研究了碱活性粉煤灰和碱活性渣在不同pH值盐酸中的溶解速率。采用XRF、XRD和FTIR对碱活性粉煤灰和碱活性矿渣中的盐酸不溶物进行了分析。碱活性粉煤灰/矿渣的地聚合反应程度可通过其盐酸不溶物的含量来确定。碱活性粉煤灰/矿渣的酸溶试验表明,在大多数情况下,添加矿渣可提高粉煤灰的地聚合度。渣量一定时,粉煤灰的反应程度随活化剂模量的增大而减小,随液固比的增大而增大。当炉渣含量较低时,活化剂浓度的增加效果更为显著。在低活化剂浓度下,粉煤灰的反应程度随矿渣含量的增加而增加。随着活化剂浓度的增加,粉煤灰最高反应度对应的矿渣含量逐渐降低。
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来源期刊
Magazine of Concrete Research
Magazine of Concrete Research 工程技术-材料科学:综合
CiteScore
4.60
自引率
11.10%
发文量
102
审稿时长
5 months
期刊介绍: For concrete and other cementitious derivatives to be developed further, we need to understand the use of alternative hydraulically active materials used in combination with plain Portland Cement, sustainability and durability issues. Both fundamental and best practice issues need to be addressed. Magazine of Concrete Research covers every aspect of concrete manufacture and behaviour from performance and evaluation of constituent materials to mix design, testing, durability, structural analysis and composite construction.
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