Graphene nanofibers: A modern approach towards tailored gypsum composites

IF 6.1 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Nanotechnology Reviews Pub Date : 2023-01-01 DOI:10.1515/ntrev-2022-0559
Alejandro Martinez Gordon, M. I. Prieto Barrio, Alfonso Cobo Escamilla
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Abstract

Abstract Energy poverty is a global challenge that demands sustainable and affordable solutions. This study investigates the use of commercial graphene nanofibers (GNFs) as a reinforcing agent in gypsum composites for energy-efficient building retrofitting. The GNFs were manually dispersed in the gypsum matrix, and the composites were fabricated by casting and curing. The thermomechanical properties were systematically studied using various characterization techniques, including scanning electron microscopy, X-ray diffraction, and thermal analysis. The results show that the addition of 1% GNFs reduces the thermal conductivity of the composites by more than 40% and improves their flexural and compressive strength by up to 23 and 42%, respectively, compared to neat gypsum. The enhancements are attributed to the effective phonon scattering of the GNFs and their ability to act as crystal seeding sites, resulting in a denser and more homogeneous structure. The dynamic thermal analysis further demonstrates that the GNF-reinforced composites could reduce heating and cooling requirements by 14 and 11%, respectively, indicating their potential for energy-efficient building retrofitting. However, the cost effectiveness and safety issues of the GNF-reinforced composites should be carefully considered before their large-scale implementation. Achieving uniform dispersion of nanoparticles in high concentrations is also a significant challenge that will be addressed in future studies.
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石墨烯纳米纤维:定制石膏复合材料的现代方法
摘要能源贫困是一项全球性挑战,需要可持续和负担得起的解决方案。本研究调查了商业石墨烯纳米纤维(GNFs)在石膏复合材料中作为增强剂的应用,用于节能建筑改造。将GNFs手动分散在石膏基体中,并通过铸造和固化制备复合材料。使用各种表征技术,包括扫描电子显微镜、X射线衍射和热分析,系统地研究了热机械性能。结果表明,与纯石膏相比,1%GNFs的加入使复合材料的热导率降低了40%以上,弯曲强度和抗压强度分别提高了23%和42%。这种增强归因于GNF的有效声子散射及其作为晶体晶种位点的能力,从而产生更致密、更均匀的结构。动态热分析进一步表明,GNF增强复合材料可分别将供暖和制冷需求降低14%和11%,表明其在节能建筑改造方面的潜力。然而,在大规模实施之前,应仔细考虑GNF增强复合材料的成本效益和安全问题。实现高浓度纳米颗粒的均匀分散也是一个重大挑战,将在未来的研究中解决。
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来源期刊
Nanotechnology Reviews
Nanotechnology Reviews CHEMISTRY, MULTIDISCIPLINARY-NANOSCIENCE & NANOTECHNOLOGY
CiteScore
11.40
自引率
13.50%
发文量
137
审稿时长
7 weeks
期刊介绍: The bimonthly journal Nanotechnology Reviews provides a platform for scientists and engineers of all involved disciplines to exchange important recent research on fundamental as well as applied aspects. While expert reviews provide a state of the art assessment on a specific topic, research highlight contributions present most recent and novel findings. In addition to technical contributions, Nanotechnology Reviews publishes articles on implications of nanotechnology for society, environment, education, intellectual property, industry, and politics.
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