Production of biodiesel from waste cooking oil using heterogeneous catalyst

Eksergi Pub Date : 2022-04-05 DOI:10.31315/e.v0i0.6132
D. Jaya, Tunjung Wahyu Widayati, Hanum Salsabiela, Muhammad Fathan Abdul Majid
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Abstract

The world's oil reserves are running low, which makes the government also implement a mandatory B30 policy starting in early 2020. With this policy, it is necessary to develop energy by utilizing renewable energy such as vegetable oil that can be converted into biodiesel. Waste cooking oil is one of the vegetable oils that has the potential to be processed into biodiesel because the use of waste cooking oil in Indonesia is still not developed. In this study, we report the yield of biodiesel from waste cooking oil with variations in the ratio of the number of moles and weight of heterogeneous catalysts. Biodiesel is made by esterification and transesterification with a heterogeneous catalyst (CaO), then a separation process is carried out to separate the biodiesel produced from the by-product in the form of glycerol. The separated biodiesel is then analyzed for density, viscosity, flash point, and pour point. The results showed that the best biodiesel was at a mole ratio of 1:24 with 3% CaO catalyst. Based on the analysis data, this biodiesel has the largest yield of 72.49% with a viscosity value of 4.9806 cSt, a flash point value of 72.5 oC, a pour point value of 0 oC, and a density value of 0.8662 g/ml and calorific value. 8837,302 cal/gram. With the results of the analysis, that are in accordance with the quality standards of SNI 7182:2015.
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利用多相催化剂从废食用油中生产生物柴油
世界石油储量正在减少,这使得政府也从2020年初开始实施强制性的B30政策。根据这一政策,有必要利用可再生能源开发能源,如可以转化为生物柴油的植物油。废弃食用油是一种有潜力加工成生物柴油的植物油,因为印尼对废弃食用油的使用尚未开发。在这项研究中,我们报道了废食用油中生物柴油的产量,以及多相催化剂的摩尔数和重量比的变化。生物柴油是用多相催化剂(CaO)通过酯化和酯交换制备的,然后进行分离过程,将副产物中产生的生物柴油以甘油的形式分离出来。然后分析分离出的生物柴油的密度、粘度、闪点和倾点。结果表明,在CaO用量为3%的条件下,生物柴油的最佳配比为1:24。根据分析数据,该生物柴油的最大产率为72.49%,粘度值为4.9806 cSt,闪点为72.5℃,倾点为0℃,密度值为0.8662 g/ml,热值为0.8662%。8837302卡/克。根据分析结果,认为符合SNI 7182:2015的质量标准。
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