Following Cu Microstructure Evolution in CuZnO/Al2O3(−Cs) Catalysts During Activation in H2 using in situ XRD and XRD-CT

Abstract

Understanding how the microstructure of the active Cu⁰ component in the commercially applicable Cu/ZnO/Al₂O₃(−Cs₂O) low-temperature water-gas shift catalyst evolves under various H₂ partial pressures in the presence/absence of a Cs promoter during thermal activation has been investigated. Time-resolved XRD and spatially-resolved XRD-CT data were measured as a function of H₂ concentration along a packed bed reactor to elucidate the importance of the zincite support and the effect of the promoter on Cu sintering mechanisms, dislocation character and stacking fault probability. The rate of Cu reduction showed a dependency on [Cs], [H₂] and bed height; lower [Cs] and higher [H₂] led to a greater rate of metallic copper nanoparticle formation. A deeper analysis of the XRD line profiles allowed for determining a greater edge character to the dislocations and subsequent stacking fault probability was also observed to depend on higher [H₂], smaller Cu⁰ (and ZnO) crystallite sizes, increased [ZnO] (30 wt.%, sCZA) and lower temperature. The intrinsic activity of Cu/ZnO/Al₂O₃ methanol synthesis catalysts has been intimately linked to the anisotropic behaviour of copper, and thus the presence of lattice defects; to the best knowledge of the authors, this study is the first instance in which this type of analysis has been applied to LT-WGS catalysts.