SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF LITHIUM SALTS OF COPPER(II) AND NICKEL(II) COMPLEXES WITH 1,3-PROPANEDIAMINE-N,N,N’,N’-TETRAACETATE

N. Drašković, D. Gurešić
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引用次数: 0

Abstract

The complexes Li 2 [Ni(1,3-pdta)]•5H 2 O and Li 2 [Cu(1,3-pdta)]•5H 2 O (where 1,3-pdta represents the 1,3-propanediaminetetraacetate anion) have been  synthesized and characterized by applying IR and UV-vis    spectroscopy. The obtained spectroscopic results of these complexes are discussed in relation to those for Mg[M(1,3-pdta)].8H 2 O complexes (M = Ni(II) and Cu(II)) of known crystal structure.
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铜(II)和镍(II)与1,3-丙二胺-N,N,N',N'-四乙酸盐配合物锂盐的合成及光谱表征
合成了Li 2 [Ni(1,3-pdta)]•5h2o和Li 2 [Cu(1,3-pdta)]•5h2o配合物(其中1,3-pdta表示1,3-丙二胺四乙酸阴离子),并用红外光谱和紫外可见光谱对其进行了表征。讨论了这些配合物的光谱结果与Mg[M(1,3-pdta)]的光谱结果的关系。已知晶体结构的8H 2o配合物(M = Ni(II)和Cu(II))。
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