The synthesis of metavivianite and the oxidation sequence of vivianite

IF 0.9 4区 地球科学 Q4 MINERALOGY Journal of Mineralogical and Petrological Sciences Pub Date : 2020-11-06 DOI:10.2465/jmps.200417
Kohei Chiba, Misaki Takahashi, E. Ohshima, T. Kawamata, K. Sugiyama
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引用次数: 1

Abstract

A mixture of metavivianite, vivianite, and spheniscidite was obtained from an aqueous solution of FeSO 4 ·7H 2 O and (NH 4 ) 2 HPO 4 at temperatures between 50 and 60 °C. The oxidation sequence of partially oxidized vivianite toward santabarbaraite or a solid solution between β – Fe 2 (PO 4 )O and Fe 4 (PO 4 ) 3 (OH) 3 , without passing through metavivianite, was also demonstrated.
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偏蓝晶石的合成及其氧化顺序
从FeSO4·7H2 O和(NH4)2HPO4的水溶液中,在50~60°C的温度下,获得了偏蓝晶石、蓝晶石和磷辉石的混合物。还证明了部分氧化的碧玄岩在不穿过偏碧玄岩的情况下向santabarbaraite或β-Fe2(PO4)O和Fe4(PO 4)3(OH)3之间的固溶体氧化的顺序。
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来源期刊
CiteScore
1.80
自引率
14.30%
发文量
5
审稿时长
>12 weeks
期刊介绍: The Journal of Mineralogical and Petrological Sciences (JMPS) publishes original articles, reviews and letters in the fields of mineralogy, petrology, economic geology, geochemistry, planetary materials science, and related scientific fields. As an international journal, we aim to provide worldwide diffusion for the results of research in Japan, as well as to serve as a medium with high impact factor for the global scientific communication Given the remarkable rate at which publications have been expanding to include several fields, including planetary and earth sciences, materials science, and instrumental analysis technology, the journal aims to encourage and develop a variety of such new interdisciplinary scientific fields, to encourage the wide scope of such new fields to bloom in the future, and to contribute to the rapidly growing international scientific community. To cope with this emerging scientific environment, in April 2000 the journal''s two parent societies, MSJ* (The Mineralogical Society of Japan) and JAMPEG* (The Japanese Association of Mineralogists, Petrologists and Economic Geologists), combined their respective journals (the Mineralogical Journal and the Journal of Mineralogy, Petrology and Economic Geology). The result of this merger was the Journal of Mineralogical and Petrological Sciences, which has a greatly expanded and enriched scope compared to its predecessors.
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