Exploring Intramolecular Methyl–Methyl Coupling on a Metal Surface for Edge-Extended Graphene Nanoribbons

Zijie Qiu, Qiang Sun, Shiyong Wang, G. B. Barin, Bastian Dumslaff, P. Ruffieux, K. Müllen, A. Narita, R. Fasel
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引用次数: 2

Abstract

Abstract Intramolecular methyl–methyl coupling on Au (111) is explored as a new on-surface protocol for edge extension in graphene nanoribbons (GNRs). Characterized by high-resolution scanning tunneling microscopy, noncontact atomic force microscopy, and Raman spectroscopy, the methyl–methyl coupling is proven to indeed proceed at the armchair edges of the GNRs, forming six-membered rings with sp3- or sp2-hybridized carbons.
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边缘延伸石墨烯纳米带金属表面分子内甲基-甲基偶联的探索
摘要Au(111)上的分子内甲基-甲基偶联被探索为石墨烯纳米带(GNRs)边缘扩展的一种新的表面协议。通过高分辨率扫描隧道显微镜、非接触原子力显微镜和拉曼光谱表征,甲基-甲基偶联确实在GNR的扶手椅边缘进行,形成具有sp3-或sp2-杂化碳的六元环。
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CiteScore
3.70
自引率
0.00%
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0
审稿时长
12 weeks
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