Modification of the Detonation Parameters of Mining Explosives Containing Hydrogen Peroxide and Aluminium Powder

IF 0.7 4区 工程技术 Q4 CHEMISTRY, APPLIED Central European Journal of Energetic Materials Pub Date : 2021-12-27 DOI:10.22211/cejem/145031
J. Paszula, A. Maranda, K. Nikolczuk, Agnieszka Giercuszkiewicz
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引用次数: 2

Abstract

Presently, due to rising environmental consciousness, numerous actions are being taken to prevent devastation of the natural environment. If explosive mixtures are manufactured in an insufficiently controlled manner, they contain too much ammonium nitrate and generate nitrogen oxides (NOx), which are both harmful for living organism and responsible for negative weather phenomena. However, the products from decomposition of hydrogen peroxide are only oxygen and hydrogen, which are both environmentally friendly. This paper presents the results of research on the impact of two types of aluminium powder on the detonation parameters of mining explosives containing hydrogen peroxide 60% as an oxidiser. The detonation velocities were measured by means of short circuit sensors. Direct measurement of the blast wave overpressure was performed with piezoelectric sensors and the positive phase impulse Central European Journal of Energetic Materials ISSN 1733-7178; e-ISSN 2353-1843 Copyright © 2021 Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, Poland 478 J. Paszula, A. Maranda, K. Nikolczuk, A. Giercuszkiewicz Copyright © 2021 Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, Poland was analyzed. Measurement of the explosive strength was made by the ballistic pendulum method for 10 g samples. The results of these experiments showed that the addition of both types of aluminium, as well as their content in the explosive mixture, have a significant impact on all of the measured parameters.
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双氧水铝粉矿用炸药爆轰参数的修正
目前,由于环保意识的提高,人们正在采取许多行动来防止对自然环境的破坏。如果爆炸混合物的制造控制不充分,它们含有过多的硝酸铵并产生氮氧化物(NOx),这既对生物有害,也会造成恶劣的天气现象。然而,过氧化氢分解的产物只有氧和氢,两者都是环保的。本文介绍了两种铝粉对含过氧化氢为氧化剂的矿用炸药爆轰参数影响的研究结果。用短路传感器测量了爆轰速度。利用压电传感器和正相脉冲直接测量了爆炸冲击波的超压。e-ISSN 2353-1843版权所有©2021 Łukasiewicz研究网络-波兰工业有机化学研究所478 J. Paszula, A. Maranda, K. Nikolczuk, A. Giercuszkiewicz版权所有©2021 Łukasiewicz研究网络-波兰工业有机化学研究所分析。用弹道摆法测定10 g样品的爆炸强度。实验结果表明,两种铝的加入及其在炸药混合物中的含量对所有测量参数都有显著影响。
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来源期刊
Central European Journal of Energetic Materials
Central European Journal of Energetic Materials CHEMISTRY, APPLIED-ENGINEERING, CHEMICAL
CiteScore
1.80
自引率
25.00%
发文量
0
审稿时长
>12 weeks
期刊介绍: CEJEM – the newest in Europe scientific journal on energetic materials It provides a forum for scientists interested in the exchange of practical and theoretical knowledge concerning energetic materials: propellants, explosives and pyrotechnics. The journal focuses in particular on the latest results of research on various problems of energetic materials. Topics: ignition, combustion and detonation phenomenon; formulation, synthesis and processing; analysis and thermal decomposition; toxicological, environmental and safety aspects of energetic materials production, application, utilization and demilitarization; molecular orbital calculations; detonation properties and ballistics; biotechnology and hazards testing CEJEM presents original research and interesting reviews. Contributions are from experts in chemistry, physics and engineering from leading research centers in Europe, America and Asia. All submissions are independently refereed by Editorial Board members and by external referees chosen on international basis.
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