Preparation of Graphene/N-Doped Carbon Nanohybrids and Their Application in Supercapacitors

Biao Xu, K. Annamalai, Tianlu Chen, Yue Chen, Y. Tao
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Abstract

Nanocarbon hybrids have become an increasing interest in recent years because of their important role in energy storage and conversion device fabrication. The objective of this study is the preparation of low-cost graphene/N-doped carbon composites (G-NC) for supercapacitor applications. G-NC samples were prepared with a two-step hydrothermal method and characterized with field emission scanning electron microscopy, 77K nitrogen adsorption and X-ray photoelectron spectroscopy. The electrochemical performance of samples was investigated with cyclic voltammetry and charge-discharge measurements in three-electrode configurations. Samples showed a sheet-type morphology and nanoporous structures. The nanohybrids had specific surface area of 350 m2g-1, delivered maximum specific capacitance of 103 F g-1 at 0.5A g-1 in 6 M KOH with good cycle stability. Low-cost G-NC nanohybrids with good electrochemical performance are promising for supercapacitor applications.
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石墨烯/N-掺杂碳纳米杂化材料的制备及其在超级电容器中的应用
近年来,由于纳米碳杂化物在储能和转换器件制造中的重要作用,人们对其越来越感兴趣。本研究的目的是制备用于超级电容器应用的低成本石墨烯/N-掺杂碳复合材料(G-NC)。采用两步水热法制备了G-NC样品,并用场发射扫描电子显微镜、77K氮吸附和X射线光电子能谱对其进行了表征。通过循环伏安法和充放电测量,在三种电极配置下研究了样品的电化学性能。样品显示出片状形态和纳米多孔结构。纳米杂化物的比表面积为350m2g-1,在6M KOH中0.5A g-1时产生的最大比电容为103F g-1,具有良好的循环稳定性。具有良好电化学性能的低成本G-NC纳米杂化物有望应用于超级电容器。
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来源期刊
Recent Innovations in Chemical Engineering
Recent Innovations in Chemical Engineering Chemical Engineering-Chemical Engineering (all)
CiteScore
2.10
自引率
0.00%
发文量
20
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