Development of Fused Deposition Modeling of Multiple Materials (FD3M) Through Dynamic Coaxial Extrusion.

IF 4.7 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-04-01 Epub Date: 2024-04-16 DOI:10.1089/3dp.2022.0197
Robert G Lahaie, Christopher J Hansen, David O Kazmer
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Abstract

Multimaterial additive manufacturing is expanding the design space realizable with 3D printing, yet is largely constrained to sequential deposition of each individual material. The ability to coextrude two materials and change the ratio of materials while printing would enable custom-tailored polymer composites. Here, the evolution of a dynamic material coextrusion process for additive manufacturing capable of printing any ratio between and including two neat input materials is described across 3 hot-end generations and 14 implemented design iterations. The designs evolved with increased understanding of manufacturing constraints associated with the additive manufacturing of metal components with internal flow bore diameters on the order of 2 mm and typical bore length around 50 mm. The second generation overcame this issue by partitioning the design into two pieces to locate the flow channel geometry at the interface between the components so that the details could be easily printed on the components' external surfaces. The third concept generation then focused on minimizing flow channel volume to reduce the average length when transitioning between materials by 92%. The third-generation design was also used to investigate the improvements in dimensional stability during annealing of acrylonitrile butadiene styrene (ABS) made possible by coextruding ABS with a polycarbonate (PC) core. The standard deviation of part shrinkage after annealing was 7.08% for the neat ABS but reduced to 0.24% for the coextruded ABS/PC components.

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动态同轴挤压多材料熔融沉积模型(FD3M)的研制
多材料增材制造正在扩大三维打印的设计空间,但在很大程度上受限于每种材料的顺序沉积。如果能在打印的同时共挤两种材料并改变材料的比例,就能实现量身定制的聚合物复合材料。在此,我们将介绍一种用于增材制造的动态材料共挤工艺的演变过程,该工艺能够打印两种整齐输入材料之间的任何比例,包括两种材料。随着对与金属部件增材制造相关的制造限制的了解不断加深,这些设计也在不断发展,这些部件的内部流孔直径约为 2 毫米,典型孔长约为 50 毫米。第二代设计克服了这一问题,将设计分为两部分,将流道几何形状定位在组件之间的接口处,这样就可以轻松地在组件外表面打印出细节。然后,第三代概念设计的重点是最大限度地减少流道体积,从而将材料之间转换时的平均长度减少 92%。第三代设计还用于研究丙烯腈-丁二烯-苯乙烯(ABS)退火过程中尺寸稳定性的改善情况,这种改善是通过将 ABS 与聚碳酸酯(PC)芯共挤而实现的。纯 ABS 退火后的部件收缩标准偏差为 7.08%,而 ABS/PC 共挤部件的收缩标准偏差则降至 0.24%。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
期刊介绍: ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.
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