Carbonation of concretes containing LC³ cements with different supplementary materials

C. Balestra, Gustavo Savaris, A. Y. Nakano, Ricardo Schneider
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Abstract

Due to the clinkerization process during the Portland cement production, large amounts of CO2 are emitted, increasing the effects related to climate change (approximately 5-10% of global CO2 emissions come from cement production), consequently, the seek for alternatives to mitigate these high emissions are necessary. The use of supplementary cementitious materials (SCM) to partial replace of Portand clinker/cement has been the subject of different research, including the use of LC3 cements (Limestone Calcined Clay Cements), where up to 50% of Portland clinker can be replaced, however, cement industry has already used othersupplementary cementitious materials with pozzolanic activities in commercial cements. In this sense, this work evaluates the performance of concretes containing LC3 mixtures with the presence of different SCM (silica fume, fly ash, sugarcane bagasse ash and açaí stone ash) regarding durability issues by carbonation. The results showed that all concretes with LC3 presented higher carbonation fronts in relation to the reference concrete, with Portland cement, due to the lower availability of calcium to react with the CO2 that penetrates into the concrete pores, so the adoption of curing procedures and coatings are recommended.
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含有不同补充材料的LC³水泥的混凝土碳化
由于波特兰水泥生产过程中的熟料化过程,排放了大量的二氧化碳,增加了与气候变化有关的影响(全球约5-10%的二氧化碳排放来自水泥生产),因此,有必要寻求替代方案来缓解这些高排放。使用补充胶凝材料(SCM)部分替代Portand熟料/水泥一直是不同研究的主题,包括使用LC3水泥(石灰石煅烧粘土水泥),其中高达50%的波特兰熟料可以被替代,然而,水泥行业已经在商业水泥中使用了其他具有火山灰活性的补充胶凝物质。从这个意义上说,这项工作评估了含有LC3混合物的混凝土在存在不同SCM(硅灰、粉煤灰、甘蔗渣灰和açaístone灰)的情况下的碳化耐久性问题的性能。结果表明,与波特兰水泥的参考混凝土相比,所有含有LC3的混凝土都表现出更高的碳化前沿,因为钙与渗透到混凝土孔隙中的CO2反应的可用性较低,因此建议采用养护程序和涂层。
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审稿时长
12 weeks
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