Crystal Structure of 6-Aza-3,9-dithiaundecane Hydrochloride

Abstract

was also observed in a series of acyclic polythioethers. 5 The title compound consists of two parts: a protonated N -H-ATU cation, ( N -H 2 -ATU) + , and a Cl – anion. Two hydrogen atoms on the N1 atom connect with the counter anion, Cl – , The crystal structure of the title compound, 6-aza-3,9-dithiaundecane hydrochloride ( N -H-ATU·HCl), was determined by X-ray crystallography. The hydrogen-bonding networks in the crystal extend along with the b and c axes to form a 2D-triple-sheet, in which the Cl – ions put between two ( N -H 2 -ATU) + sheets. The compound was crystallized in an orthorhombic system as: Pccn , a = 25.0091(4), b = 5.39364(10), c = 9.37759(19)Å, Z = 4, V = 1264.94(4)Å 3 . The R 1 and wR 2 values were 0.0341 and 0.0880, respectively, for 1162 reflections.